草酸处理制备抗氧化的纳米铜导电油墨-包装工程.PDFVIP

包装工程 第36卷 第23期 34 PACKAGINGENGINEERING 2015年12月 草酸处理制备抗氧化的纳米铜导电油墨 万云蕾，周奕华，钱俊，苏亚兰 （武汉大学，武汉 430072） 摘要：目的目的研究制备抗氧化纳米铜的化学方法，以提高纳米铜油墨的导电性。方法方法 液相还原法制备 纳米铜，在乙醇中用草酸处理后，混合丙烯酸树脂配成导电油墨，丝网印刷于PI膜上。对纳米铜和铜 膜进行XRD，TEM，SEM，XPS表征。结果结果 经草酸处理后，铜膜导电性得到显著提高，250℃真空烧结 1h，电阻率低至24.1 μΩ·cm。结论结论 经草酸处理的纳米铜油墨具有抗氧化性，导电性满足印刷电子 要求。 关键词：纳米铜；导电油墨；草酸；抗氧化 中图分类号：TS802.3 文献标识码：A 文章编号：1001-3563（2015）23-0034-05 Preparation of Antioxidative Copper Conductive Ink by Oxalic Acid Treatment WANYun-lei，ZHOUYi-hua，QIANJun，SUYa-lan （Wuhan University ，Wuhan 430072 ，China） ABSTRACT ：To improve the conductivity of nano-copper ink, a simple chemical process was presented to synthesize oxidation-resistant copper nanoparticles. The copper nanoparticles synthesized by aqueous reduction method were treated by oxalic acid in ethanol. And the particles were then mixed with acrylic resin to prepare conductive ink which was used to fabricate conductive copper patterns on polyimide films by screen printing. TEM, SEM, XRD and XPS were conducted to characterize the synthesized copper nanoparticles and films. After oxalic acid treatment, the copper film showed higher conductivity and its resistivity was as low as 24.1 μΩ·cm after being annealed in the vacuum oven at 250 ℃for one hour. With superior oxidative stability and good conductivity, the copper conductive ink treated by oxalic acid is proper for printing electronics. KEY WORDS ：copper nanoparticles ；conductive ink ；oxalic acid ；oxidation-resistance 印刷电子是近年国际的研究热点之一。印刷电子 题[6]。纳米铜的导电性仅次于纳米银，价格相对低廉， 技术具有节能环保、成本低等优点，可制造柔性电子， 电子迁移效应小，是合适的替代品。 且产品尺