25- Solubility -Chm II：25 -溶解- CHM II.pptVIP

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25- Solubility -Chm II：25 -溶解- CHM II.ppt

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25- Solubility -Chm II：25 -溶解- CHM II.ppt

Drill: Calculate the solubility of CaCO3 in water. Ksp = 4.9 x 10-15 Calculate the solubility of PbI2(s) in 0.010 M NaI Ksp = 3.2 x 10-8 The Really Bad Solubility Problems Aqueous NaI is added (dropwise) to a solution of 0.10 M AgNO3(s) 0.10 M CuNO3 AgI Ksp = 1.0 x 10-16 CuI Ksp = 5.1 x 10-12 Aqueous KCl is added (dropwise) to a solution of 0.10 M AgNO3 0.10 M Cu(NO3)2 AgCl Ksp = 1.8 x 10-10 CuCl2 Ksp = 5.1 x 10-12 Drill: Calculate the solubility of PbS(s) Ksp = 1.0 x 10-28 Review Calculate the solubility of PbCl2(s) Ksp = 1.6 x 10-5 Calculate the solubility of Sc(OH)3(s) Ksp = 2.7 x 10-31 Calculate the solubility of Ca(OH)2. Ksp = 4.0 x 10-6 Calculate the pH of Li2CO3 Ksp = 8.2 x 10-4 Ka1 = 4.4 x 10-7 Ka2 = 4.7 x 10-11 Calculate the solubility of AgI(s) in 0.20 M NaI Ksp = 1.5 x 10-16 The solubility of MX2(s) is 2.0 x 10-5 M. Calculate its Ksp Aqueous MgCl2 is added (dropwise) to a solution of 0.20 M KOH 0.10 M K2SO4 Mg(OH)2 Ksp = 5.0 x 10-6 MgSO4 Ksp = 5.6 x 10-5 10.0 mL 0.050 M KCl is added to 15 mL 0.060 M Pb(NO3)2. Ksp PbCl2 = 1.7 x 10-5 Will a ppt form? Drill: The solubility of YF3 is 2.0 x 10-8. Calculate the value of Ksp. Drill: Determine the KQ/HQ ratio to make a buffer solution with a pH of 4.70 Ka for HQ = 3.0 x 10-5 Drill: Calculate [H2Q], [HQ-], [Q-2], [H+], pH of 0.20 M KHQ.Ka1 = 2.0 x 10-4 Ka2 = 8.0 x 10-9 Solubility Solubility The amount of one substance that will dissolve in another Saturated Solution When the maximum amount of one substance is dissolved in another Precipitation When more than the maximum amount of solute is added to a solution, a ppt will form Precipitation When dissolved particles join together forming a new phase and exit the solution Precipitate (ppt) The new phase that forms and leaves the solution Ppt Examples Water vapor combining to form rain Dissolved ions combining to form a solid Write the equilibrium expression for AgCl(s) Ag+ + Cl- Solubility Product MX(s) M+(aq) + X-(aq) Ksp =[M+][X-] Solubili