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掺镍pt001纳米多孔薄膜对甲醇的电催化氧化-中国科技论文在线
中国科技论文在线
摻镍Pt(001)纳米多孔薄膜对甲醇的电催
#
化氧化
鲁乐业,张祎杨,魏明龙,张叶,翟文静,邢玉陟,邱晓燕**
5 400715
摘要:MgO Pt(001)
Pt
Pt(001)45 %Pt(001)
Ni
10 Pt(001)
29mA/cm2 1000 摻Pt(001)
关键词:
中图分类号:O621
15 Ni-modified Pt(001) porous film as an electrocatalyst for
electrooxidation of methanol in alkaline media
LU Leye, ZHANG Yiyang, Wei Minglong, ZHANG Ye, QU Wenjing, XING Yuzhi,
QIU Xiaoyan
(Southwest university,Physics and Technology schoolChong Qing,400715)
20 Abstract: In this work, porous Pt (001) nanofilm modified with Ni nano-particles, grown on MgO
substrate by magnetron sputtering, is studied as one of electrocatalytists for electrooxidation of methanol.
Micro-structural characterizations reveal that the pores ratio of Pt(001) thin film increases with the
increase of well-controlled oxygen fraction in the deposition ambient. Pt(001) thin film deposited with
45%-oxygen fraction exhibits percolating Pt networks infiltrated with interconnected nano-sized pores.
25 After coating one layer of Ni nano-particles, the 45%-oxygen deposited Pt(001) porous film acts as an
electrocatalyst for electrooxidation of methanol in alkaline media, a large catalytic current of 29mA/cm2
and a current-lasting time of more than 1000s are obtained, showing the promising applications of
electrocatalyst for electrooxidation
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