含脲环类高湿附着力促进剂的水性涂料发展状况及研究.pdfVIP

含脲环类高湿附着力促进剂的水性涂料发展状况及研究 孟声韦欣华 北京工业大学环境与能源工程学院应用化学系100022 摘要：本论文研究的乳胶涂料湿附着力促进剂(WAM)是一种含有脲环类单体，它是由烯丙基缩水甘 AEEU是由二乙烯三胺和脲反应获得，影响其产率的因素主要有时旬、温度及反应物投料比。当实验放大 时，最佳工艺条件发生规律性变化；本文着重研究了放大了十倍时白l】变化规律，为今后中试奠定了基础。另 外，将GMA与AEEU合成w姗添加到全丙、苯丙和硅丙乳液中，制成乳胶涂料并测试性能。通过和以 AGE为原料制得的WAM加入到乳液中测试出的性能相比基本相同，都可以显著提高涂料的湿附着性能。从 经济上考虑，用GMA代替AGE作为合成wAM的原料更为恰当。 关键词：乳胶涂料湿附着力促进剂，湿附着力性能，甲基丙烯酸缩水甘油酯，烯丙基缩水甘油醚，2一 胺乙基亚乙基脲 adhesion latex anne ureidomomomerswhich Abstract：Wet promoters(WAM)forpaintsessentiallycyclic anne thereactionof HIea(AEEU)withether(AGE)or producedby 2-aminoethylethylene allylglycidyl glycidyl of canbemadethereaction andHieThemainfactors methacrylate(GMA)．AEEUby diethylenetriamine itsreactionratioare andthe ofreactants．ⅥThenthe is affecting time，temperatureproportion experimentmagnified， to in thesis thebest condition ordermake formiddle process changes．In future，thismainly pave experiment discussestheruleof tentimes．In madefromthereactionofGMAandAEEUisadded magnifying addition，WAM to and latex the oftheselatex aretested． all-acrylic，benzene—acrylic silicon-acrylicpaints，andproperties paints resultsare thesameastheWAM’Smade bothcan increase Furthermore，the from essentially AGE．They greatly wetadhesion oflatex fromthe of GMAinsteadofAGEto property paints．But respecteconomy，using prepare WAMmore is preferred． Words