表面修饰碳纳米管环氧树脂复合材料的界面结构与性能-高分子化学与物理专业论文 word格式.docx

Secondly, controlled and uniform silica coating on MWNT was successfully achievedvia sol-gel process to fabricate silica coated MWNT coaxial nanocable (SiO2@MWNT).Then, SiO2@MWNT hybrid fillers were compounded with CYD-128 epoxy resin to fabricate SiO2@MWNT/epoxy composites. The effect of the SiO2 coating layer on the flexural and dynamic mechanical, thermal and electrical conductive as well as thermal stable properties of the composites were studied. The results showed that aggregates of MWNT were greatly reduced to realize good dispersion of MWNT in epoxy matrix and the interfacial interaction between MWNT and epoxy matrix was improved. Hereby, the flexural and dynamic mechanical, as well as thermal stable properties of the composites were enhanced. Moreover, the SiO2 coating layer also realize the modulus matching between stiff MWNT and soft epoxy matrix to reduce the interfacial thermal resistance, as a result of which, the final thermal conductivities of the composites were obviously increased. Simultaneously, the electrical insulating SiO2 layer also provided the SiO2@MWNT/epoxy composites with high electrical resistivitites.Moreover, controlled and uniform titania coating on MWNT was also successfully achieved via sol-gel process to fabricate titania coated MWNT coaxial nanocable (TiO2@MWNT). Then sintering procedure was taken to produce a crystallized anatase coating layer.In the final part, TiO2@MWNT was compounded with CYD-128 epoxy resin to fabricate TiO2@MWNT/epoxy composites. The flexural mechanical, thermal and electrical conductive properties of the TiO2@MWNT/epoxy composites were studied. The TiO2 coating layer improved the dispersion of MWNT in epoxy matrix. Herein, the flexural strength and modulus of the composites were obviously improved. In addition to alleviate the modulus mismatching between stiff MWNT and soft epoxy matrix, the instinct relative high thermal conductivity of crystal TiO2 coating layer could make another contribution to the im