单相多铁性bifeo3及其掺杂化合物的合成与物性研究-材料物理与化学专业论文.pdf.docxVIP

Study on preparation and properties of the multiferroic BiFeO3-based compoundsFang Lin (Materials Physics and Chemistry)Abstract: Multiferroic materials, which simultaneously exhibit two or more ferroic natures(such as ferroelectricity, ferromagnetism), and more importantly, magnetoelectric coupling effect, have stimulated increasing interest in research for the novel devices such as actuators, sensors, transducers and memories. As a representative single-phase multiferroic material, perovskite-type BiFeO3 (BFO) may exhibit ferroelectric and antiferromagnetic properties simultaneously at room temperature. In view of the defects of BFO, in this dissertation, we mainly report the preparation of BFO and the effects of La doping and magnetic field on the structure and properties of BFO. Main works are as following:Chapter 1: Introducing the history and present status of research on multiferroic materials. Discussing the structure, properties and existed problems of multiferroic material BFO.Chapter 2: In view of volatilty of Bi, preparation of BFO by choosing different ratio of Bi:Fe and Bi1-xLaxFeO3 with x=0, 0.05, 0.1, 0.15, 0.2, and obtainng the best content with Bi at x=1.02) and La at x=0.1.Chapter 3: Preparing Bi0.9La0.1FeO3 ceramics in the magnetic field of 0.5T and 0T by solid reaction, respectively. It is found that the compactness of samples is improved, particle scale is minished, and, polarization of BLFO is improved correspondingly.Chapter 4: Preparing the compound of Bi0.9La0.1FeO3 and CoFe2O4 (CFO) by solid-phase reaction in the magnetic field of 0.4T and 0T respectively. By analyzing it is found that the ferroelectric and magnetic properties are improved greatly.Chapter 5: Summarizing the previous work, and looking for the future word briefly.Key words: Multiferroic, BiFeO3 , Solid-phase reaction, Sintered in magnetic fieldII目 录第一章绪论 ................................................. 11.1 引言 ...............................................................