稀土β成核剂改性无规共聚聚丙烯的流变性能与结晶性能研究-高分子化学与物理专业论文.docx

稀土β成核剂改性无规共聚聚丙烯的流变性能与结晶性能研究Rheologyandcrystallization propertiesof βnucleating agentmodified ofPPRABSTRACTPPisexcellentforitscomprehensiveperformance,butsomedefectssuchaslowimpactstrength,heat shrinkableetc,whichlimittheapplicationsofPP.Improvecomprehensiveperformanceorcertainaspects performanceofPP through chemicalorphysicalmodification can expand the applicationrangeofPP.ThispaperresearchPPRwhichmixedwithsixkindsrareearthbetanucleatingagent(WBG-1,WBG-2,WBG-3,WBG-4,WBG-5,WBG-6)respectively,andanalysethepropertiesofmechanics, crystallization, rheology.BytheresearchofmechanicalpropertiesofthePPRmodifiedbythesixnucleatingagent,wefoundthat:thesixβnucleatingagentallcanimprovemechanicsperformanceofPPR.ElongationofPPRmodifiedby WBG-1(0.3%)、WBG-2(0.1%)andWBG-6(0.1%) respectivelyincreasefrom256.3%to 945.4%,747.1% and411.0%; PPR modified by WBG-3 and WBG-5 have good elongation both about 700% at any content(0.1%-0.5%);buttheelongationismorethan700%whenWBG-4(0.1%-0.3%)mixedintoPPR,alsotheimpactstrengthatroom(25oC)andlowtemperature(-30oC)increase.ThesectionofPPRappearsductilefracture toughnessnestsobviously aftermix anucleatingagent.Crystallizationinfluencesbytheconditionsuchastemperature,shearandthermalhistorybesides concentrationofnucleatingagent,westudiedthecrystallizationbehaviourofPPRanditsmodifiedproducts. Theresultsshowthat, purePPRcrystallizesslowly,theinterfaceofsphaerocrystals isobvious, andthe crystallizerateofmodifiedPPRwasspeedup,thesizeofsphaerocrystalswasdiminish,alsoitappearsnointerface, form irregular flower shape crystal; modified PPR by WBG-1(0.3%)、WBG-2(0.1%)、WBG-3(0.1%)appearestwomoltenabsorptionpeaksfromDSCmoltencurves,andthe?βwasabout54.2%、50.6% and45%respectively, andtheβnucleationeffectisbetterobviously;theKxofmodifiedPPRareabout 29.03%,30%and 30%respectively byWAXD,and its consistentwith mechanicalproperties andDSC income.Themachining andextrusion rheologicalbehaviourofPPRareinfluentialbynucleatingagent, we conductastudyofPPRmodifiedby