有机溶剂对环己烯催化水合反应性能的影响-化学工艺专业论文.docx

有机溶剂对环己烯催化水合反应性能的影响EFFECT OF ORGANIC SOLVENT ON THE ACTIVITY OF CYCLOHEXENE HYDRATIONABSTRACTThe liquid-phase cyclohexene hydration to produce cyclohexanol is an atom economic reaction. It can be a clean production by developing solid catalyst. However, this process suffers from the low cyclohexanol yield. Effect of morphology and particle size of HZSM-5, organic solvent and reaction conditions on the activity of cyclohexene hydration was studied in this paper.Firstly, HZSM-5 zeolite was synthesized by dynamic hydrothermal synthesis method. X-ray diffraction (XRD) characterization results showed that the crystallinity of HZSM-5 was high. Effects of molar ratio of silica to alumina, pH regulators, crystallization temperature, surfactants and crystallization time on morphology and particle size of HZSM-5 were represented by scanning electronic microscopy (SEM) characterization. HZSM-5 with high molar ratio of silica to alumina had more regular morphology. The pH regulators had little influence on morphology and particle size of HZMS-5. HZSM-5 with more regular morphology and smaller particle size could be prepared by varying-temperature synthesis method. The monodisperse HZSM-5 shaped like cakes was synthesized with suitable surfactants as additives. The average particle size was0.5 μm. The particles would grow up to 3.0 μm with the crystallization time prolonged. The monodisperse HZSM-5 shaped like cakes with small particle size showed excellent catalytic activity on cyclohexene hydration.Secondly, the reaction conditions of indirect cyclohexene hydration catalyzed by sulfuric acid were optimized. Under the optimal reaction conditions: sulfonation time 1h, molar ratio of sulfuric acid to cyclohexene 3:1, concentration of sulfuric acid in hydrolysis 25%(wt%) and sulfonation concentration of sulfuric acid 85%, the cyclohexene conversion was 70.7%, and the cyclohexanol selectivity was 97.9%. Phosphotungstic acid showed more excellent catalytic activity in the system of