稀土镁合金微观组织及腐蚀性能的分析-材料加工工程专业论文.docx

进一步提高合金的耐腐蚀性能。两种合金电化学腐蚀实验结果表明AZ80 镁合金及AZ80+1%Nd镁合金的析氢腐蚀为阳极控制，其腐蚀速率的增加伴随相应的腐蚀电位变负，合金表面极化度越明显，合金腐蚀速率越低，阳极控制越明显，其耐腐蚀性能越强。综上所述，时效态AZ80+1%Nd镁合金的耐腐蚀性能最佳。关键词：AZ80镁合金，Nd，热处理，微观组织，腐蚀性能ResearchaboutMicrostructureandcorrosionpropertiesof MagnesiumRare-EarthAlloysAbstractResearchabouttheapplicationofadvancedmagnesiumalloysinautoIndustryhasbeen increasinginthepastdecade.High-ductilityandheat-resistancemagnesiumalloyshavebeen impovedgreatly.However,thepoorcorrsionresistancehasbeenoneofthemainobstaclesthat impedetheapplicationofmagnesiumalloysinpracticalenvironments.Atpresent,theresearch abouttheinfluenceofNdonthecorrosionresistanceofMg-Al-Znalloyhasnotbeenenough perfect.Therefore,itisnecesssrytoresearchheattreatmentprocessforthecorrosion mechanismofAZ80magnesiumalloyContainingNd.TheinfluenceofNdcontentonthecorrosionbehaviourofAZ80magnesiumalloyin as-cast(F),solution-treated(T4)andpeak-aged(T6)conditionsin5%NaClsolutionwas investigatedbyimmersiontestsandelectrochemicalmeasurements.Thecorrosionbehaviours ofAZ80andAZ80+1%Ndwerecomparedandthereasonforthehighercorrosionresistance ofthus alloywas discussed.Theresultsshowedthat:1%Ndadditioncaneffectivelyimprovethemicrostructureof AZ80magnesiumalloy,andtheMg17Al12phaseofreticularformationwastransformedinto dispersedandfineboneshape,aswellasresultsinformationofneedle-likeAl3Ndphaseand oftheblockAl2Ndphasewithhighmeltingpointinmagnesiumalloy.TheMg17Al12phaseare solubledintheα-Mgsubstrate aftersolution-treated,andanewphaseofAl3Mg2phase appearedfromthesaturatedsolidsolution,Al3NdphaseandAl2Ndphasedoesnot dissolved.Theprecipitatedphasedistributedcontinuouslyinzhecrystalunderthehigh temperaturepeak-agedcondition,theprecipitatedphasetransformedintodispersedatthegrain boundaryunderthelowtemperaturepeak-agedcondition.Thebestsolution-treatmentprocess isdeterminedforAZ80magnesiumalloyis420temperatureby12h,whichbestpeak-aged processis175temperatureby28h,whichpeakhardnessis75.5HB.Thebest solution-treatment process is determined for AZ80+1%Nd m