MgO单晶点缺陷的X射线漫散射研究-硕士论文.docVIP

分类号 密级 UDC 硕 士 学 位 论 文 MgO单晶点缺陷的X射线漫散射研究 指导教师姓名 学 位 类 别 理学硕士 学 科 名 称 凝聚态物理 研 究 方 向 磁性功能材料 论文提交时间  摘 要 MgO单晶具有Bragg衍射角变小，说明晶格常数变大。200 kGy剂量辐照样品的(311)衍射峰有劈裂现象，可能暗示了复杂缺陷的形成。X射线漫散射主要反映弱畸变区。在弱畸变区，晶格常数变大，是间隙原子造成的结果。(3) 200倒易阵点周围等强度图与对偶极力缺陷计算的漫散射等强度曲线相吻合，表明MgO单晶经辐照引入了110劈裂间隙原子。由缺陷的稳定性分析知，辐照MgO单晶中还应存在100劈裂间隙原子。间隙原子的形成总是伴随着空位的产生，因此，辐照MgO单晶中也必然存在空位。黄昆漫散射来源于应变区域，应变的区域越大，黄昆漫散射强度也就越大。与间隙原子相比，空位引起的晶格畸变小很多，引起的X射线漫散射强度也要更小。因此，X射线漫散射技术不能给出更多有关空位的信息。 关键词： Abstract d0 ferromagnetic semiconductor seems most likely to be applied in spintronics device due to its ferromagnetism at high temperature, has caused widespread research. Generally， this kind of magnetism is considered to come from the defects in material, but systemic quantitatively study on the relationship between d0 magnetism and defects is seldom carried out. Research results showed that MgO single crystal with defects presented d0 ferromagnetism. The simple face centered cubic crystal structure of MgO single crystal helps people completely characterize its defect configuration. Therefore, the detailed point defect configuration combined with magnetic properties is helpful to reveal the mechanism of d0 ferromagnetism. In this paper, point defects configuration of irradiated MgO single crystal was investigated by means of X-ray diffuse scattering technique. Applying the obtained X-ray diffuse scattering intensity formula based on the theory of lattice dynamics, we calculated the X-ray diffuse scattering intensity caused by single crystal cubic defects and double-force defects in MgO single crystal. High-quality (001) oriented MgO single crystal after irradiation treatment by 60Co with dose of 100 kGy, 150 kGy and 200 kGy was used in this paper.