cus纳米复合物的制备及其仿酶催化性能的分析word格式论文.docxVIP

AbstractThe thesis aimed at studying the biomimetic catalysis research based on the peroxidase-like properties of CuS. Firstly using biological macromolecules to modifyCuS surface，secondly using simple organic compound as templates to control CuSstructure ， and proposed different synthesis methods for CuS nanomaterials ， developing the research frontier field nanomaterials as enzyme mimetics combined with the enzyme-like properties of CuS. CuS nanomaterials with different structures and excellent performance were synthetized by using supramolecular self-assembly method.This thesis employed bovine serum albumin (BSA) and metal organic framework material (ZIF-8) as macromolecular template ， synthesized uniform particle size copper sulfide (CuS) and flower-sphere like CuS，respectively. XRD and FESEM was taken to strengthen the monitoring of the synthesis reaction process，greatly improved the synthesis progress of the work and better controlled the reaction conditions. And some morden physical and chemical methods like：field emission scanning electron microscope(FESEM)，transmission electron microscope (TEM) have been further exploited to characterize the nanocrystalline structures of samples， fourier transform infrared spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS)，and the specific surface area test (BET) to describe composition and chemical characteristics of the samples which would be helpful to explain CuS catalytic degradation mechanism. The results indicated that the spherical flower CuS had better microstructure and enzyme-like catalysis activity.With mild experimental conditions，BSA template method studied an efficientway to synthesize organic-inorganic hybrid materials by the coordinating interaction of functional groups；And realized CuS surface modification，successfully prepared CuS nanomaterial with organic complexes character which can’t get by conventionalchemical methods, and better controlled the structure and composition of inorganic nanom