frp拉挤制品用环氧树脂基体的湿热耐久性能分析word格式论文.docxVIP

摘 要研究 FRP 复合材料在湿热环境下的耐久性能，对 FRP 在土木工程领域的设 计与应用具有重要的工程与科学意义。树脂基体的耐久性能是决定 FRP 复合材 料耐久性能的关键因素之一，本文研究了用于拉挤制备 FRP 土木工程制品（如 FRP 增强筋、FRP 板、FRP 型材）的三种环氧树脂在不同温度水及强碱溶液浸 泡 6 个月后的水吸收扩散行为及其力学性能变化。本文的主要研究内容，包括：环氧树脂体系在不同温度蒸馏水浸泡下的性能演化结果表明，苯酐固化环 氧树脂体系内的水吸收率远小于苯二甲胺固化环氧树脂体系，但后者的力学性 能及其在不同温度浸泡后的力学性能保留率均高于苯酐体系；同甲基六氢邻苯二甲酸酐相比，甲基四氢邻苯二甲酸酐固化环氧体系的抗弯强度退化更为明显；在蒸馏水浸泡下，三种环氧树脂体系的抗弯模量变化较小。对蒸馏水浸泡 6 个月的苯酐固化环氧树脂试样进行 60oC 烘干，结果发现， 高温浸泡试样（如≥60oC）的脱水率低于吸水率，说明高温浸泡下，部分水分 子与环氧树脂分子间形成较强的价键结合，不能在较低温度下脱水；烘干后， 苯酐固化环氧树脂脆性增加，抗弯强度显著下降。对环氧树脂体系在不同温度碱溶液浸泡下的性能演化的研究结果表明，两 种苯酐固化体系树脂在高温下发生明显水解，甲基四氢苯酐固化体系水解程度 高于甲基六氢苯酐固化体系；间苯二甲胺固化环氧树脂体系表现出较好的耐碱 性能，树脂无明显水解现象，同时，其强碱溶液浸泡对其力学性能的影响也较小。烘干后苯酐固化试样的力学性能均有所下降，但下降幅度小于水浸泡试样。 通过对三种固化树脂体系耐久性能的比较，可以发现，间苯二胺固化环氧树脂体系的基本力学性能、耐水及强碱性能均优于苯酐固化体系。关键词：环氧树脂；耐久性能；抗弯性能；显微硬度；玻璃化转变温IAbstractDurability for FRP composite under hygrothermal conditions has important scientific and engineering significance for the application and design of FRP in civil engineering. The long term property variation of resin matrix is one of the the key factors controlling the durability of FRP composites. In view of this, the present thesis studied the durability of three kinds of resin systems through testing the changes of water absorption, diffusion behavior and their mechanical properties, when exposed to distilled water and alkaline solutions. In water and alkali solution of different temperatures, the specimens have been soaking for 6 months. The research contents and conclusions are summarized as follows.Anhydrides cured epoxy resin systems soaked in the water possesses a much lower water uptake than that of m-xylylenediamine cured epoxy resin. Howerver, the systems cured with m-xylylenediamine exhibits much better resistance to water and alkaline solution, which is indicated by the much higher retention of mechanical properties after soaking. Compared with methylhexahydrophthalic anhydride (MHPTA), methyltetrahydrophthalic anhydride (MTPTA) cured epoxy system shows more evidient in the degradation of the tensile st