基于二芳乙烯固态荧光开关的设计 合成及性质分析-design, synthesis and property analysis of solid-state fluorescent switch based on diarylethene.docxVIP

三 峡 大 学 硕 士 学 位 论 文  PAGE 4 万方数据 Abstract The switching and tuning of the solid-state emission is of great interest both in the field of fundamental research and for practical applications in memory, molecular machine, and displaying devices. The external stimuli are usually light, sound,electricity, and mechanical force, among which light-controllable mode is the most favorite one because of its convenience over other stimuli. Although many light-sensitive materials are utilized to fabricate memory devices, bistable photochromism of diarylethene (DTE) is considered as most promising due to DTEs various advantages over other photochromic systems, such as excellent fatigue resistance, fast response, high quantum yields, thermal irreversibility, large changes of the absorption wavelength between the two isomers, and facile synthesis. Multifunctional fluorescent molecules combining DTE units have been successfully investigated with the aimed applications in optical memory. Combining the solid-state fluorescence of solid emitters and photochromism of DTE, ultrahigh-density storage may be realized, if the fluorescence of the chromophore matches the absorption of the close isomer of DTE. The main work includes the following aspects: Chapter One: The type of current fluorescent switches were summarized , including the research of solid-state fluorescent switches , characteristics and application in practice. Chapter Two: Design, synthesis of photochromic DTE derivatives containing a carboxyl group and investigated the solid-state fluorescent molecule switch’s properties of the self-assemblies of DTE molecules with BOPIM dye by intermolecular hydrogen bond。 Chapter Three: Design, synthesis of small molecules solid-state fluorescent molecule switch of diarylethene linked with chromophore covalently and explore its photophysical properties and photochromic properties; Keywords: Diarylethene solid-emissive molecular switches self-assemblies  目录  HYPERLINK \l