羧甲基化沙柳木粉负载纳米零价铁吸附水中Pb2.DOC

羧甲基化沙柳木粉负载纳米零价铁吸附水中Pb2+ 扈佳琪*，王丽 （内蒙古农业大学 材料科学与艺术设计学院，内蒙古 呼和浩特 010018） 摘要：以羧甲基化沙柳木粉（CMS）为载体，采用液相还原法制备羧甲基化沙柳木粉负载纳米零价铁（NZVI/CMS）吸附剂。采用SEM、FTIR、XRD和TEM对纳米零价铁（NZVI）和NZVI/CMS的微观结构进行了表征。考察了不同吸附条件对NZVI和NZVI/CMS吸附Pb2+性能的影响。表征结果显示：NZVI成功负载在CMS上，负载后的NZVI的分散性明显提高，团聚现象得到有效解决，CMS起到分散NZVI颗粒的作用。吸附结果显示：当NZVI和NZVI/CMS的投加量分别为0.05 g和0.01 g，Pb2+初始质量浓度分别为600 mg/L和400 mg/L，吸附时间为120 min，吸附温度为30℃，Pb2+溶液4.5和4.0时，NZVI和NZVI/CMS对Pb2+的吸附量最大，分别为390.30 mg/g和535.50 mg/g。循环吸附实验表明，NZVI的吸附量从第一次的390.3 mg/g下降到第四次的98.6 mg/g，NZVI/CMS的吸附量从第一次的535.5 mg/g下降到第四次的469.7 mg/g，NZVI/CMS呈现出比NZVI更优越的循环使用性能。 关键词：沙柳；纳米零价铁；吸附；还原；Pb2+ 中图分类号：X52 文献标识码：A Adsorption Properties of Pb2+in Aqueous Solution by Carboxymethyl Salix Psammophila Powder Supported Nanoscale Zero-Valent Iron HU Jiaqi*, WANG Li (College of Material Science and Art Design, Inner Mongolia Agricultural University, Hohhot 010018, Inner Mongolia, China) Abstract: The carboxymethyl salix psammophila powder(CMS) as carrier, the carboxymethyl salix psammophila powder supported nanoscale zero-valent iron(NZVI/CMS) was prepared by using liquid phase reduction method. The micro structures of nanoscale zero- valent iron(NZVI) and NZVI/CMS were characterized by means of SEM, FTIR, XRD and TEM. The effects of different adsorption conditions on adsorption properties of NZVI and NZVI/CMS for Pb2+ were studied. The characterization results show that NZVI was loaded on the CMS successfully, and the NZVI were scattered obviously on CMS, reunion phenomenon had been resolved effectively, CMS played a role in dispersing NZVI particles.The adsorption results showed that the adsorption capacities of NZVI and NZVI/CMS reached a maximum of 390.30 mg/g and 535.50 mg/g as the dosage was 0.05 g and 0.01 g respectively, the initial mass concentration of Pb2+ was 600 mg/L and 400 mg/L respectively, the adsorption time was 120 min, the adsorption temperature was 30℃ and the pH of Pb2+ solution was 4.5 and 4.0 respectively. The cyclic adsorption experiments show that, the adsorpti