Summary of Chemical Reaction Engineering 化学反应工程 培训资料.pptVIP

化 学 反 应 工 程 Quantitative Calculation: The definition of the instantaneous and the overall fractional yield of R, 化 学 反 应 工 程 For PFR: For MFR: 化 学 反 应 工 程 How to obtain the maximum concentration of the desired product R ? 化 学 反 应 工 程 化 学 反 应 工 程 Chapter 8 Potpourri of Multiple Reactions Qualitative Discussion (A ? R ? S): For irreversible reactions in series the mixing of fluid of different composition is the key to the formation of intermediate. The maximum possible amount of any and all intermediates is obtained if fluids of different compositions and at different stages of conversion are not allowed to mix. No backmix ! 化 学 反 应 工 程 Quantitative Treatment 化 学 反 应 工 程 Irreversible Series-Parallel Reactions or 化 学 反 应 工 程 Irreversible Series-Parallel Reactions Irreversible series-parallel reactions can be analyzed in terms of their constituent (组成的) series reactions and parallel reactions in that optimum contacting for favorable product distribution is the same as for the constituent reactions. 化 学 反 应 工 程 化 学 反 应 工 程 Chapter 9 For single reactions, the optimum temperature progressions are: Temperature and Pressure Effects For irreversible reactions and endothermic reversible reactions, the highest allowable temperature should be used. For exothermic reversible reactions, the operation should start at a high temperature which decreases as conversion rises. Obtain the optimum operating line or operating point ! 化 学 反 应 工 程 (-rA) – XA – T Chart 化 学 反 应 工 程 Figure 9.5 Operating lines for minimum reactor size. 化 学 反 应 工 程 Adiabatic operations 化 学 反 应 工 程 Figure 9.9 Best location for the adiabatic operating line. For plug flow, a trial and error search is needed to find this line; for mixed flow, no search is needed. 化 学 反 应 工 程 Nonadiabatic operations 化 学 反 应 工 程 Figure 9.12 Ways of approaching the ideal temperature profile with heat exchange: (a) and (b) exothermic reactions; (c) endothermic reaction. Summary of Chemical Reaction Engineering 化 学 反