金纳米粒子的制备及其在光谱研究中的应用-preparation of gold nanoparticles and its application in spectral research.docxVIP
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金纳米粒子的制备及其在光谱研究中的应用-preparation of gold nanoparticles and its application in spectral research
ultra-visible spectrophotometric to determining reduced GSH was established. At the optimal conditions, GSH can be selectively determined in the range of 0.17μM (R=0.98588) with the detection limit of 0.17μM. Many relative amino acids will not interfere with the determination.(3) In the third part of the paper, under the condition of natural pH ,a novel strategy for using gold nanoparticles modified with reduced glutathione (GSH) for sensing heavy metalsions(Cu2+) was reported. The GSH-GNPs can bind withCu2+ more selectively over other metal ions (Fe3+、Ca2+、Zn2+、pb2+、Hg2+、Na+、K+), leading to a prominent color change. The obtained results proved that this method achieved high sensitivity with low interference.Keywords: gold nanoparticles; colorimetric method; reduced glutathione; Cu2 +V目录摘要................................................................................................................ IIAbstract ............................................................................................................IV第一章 绪论..................................................................................................11.1 贵金属纳米粒子基本理论.....................................................................11.2 金纳米粒子综述.....................................................................................31.2.1 金纳米粒子的研究现状与进展..................................................31.2.2 金纳米粒子的特性......................................................................41.2.3 金纳米粒子的制备及表征........................................................101.2.4 金纳米粒子在生物分子及重金属离子检测中的应用............121.3 本论文的研究内容与意义...................................................................25第二章 金纳米粒子的种子生长法制备及其在 SERS 光谱中的应用 272.1 引言.......................................................................................................272.2 实验部分...............................................................................................282.2.1 实验材料与试剂...............................................
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