扩散渗析用pvanano-tio2杂化膜的制备及性能研究论文-preparation and properties of pvanano - tio _ 2 hybrid membrane for diffusion dialysis.docxVIP

研究生优秀毕业论文扩散渗析用PVMnaIlo-Ti02杂化膜的制备及性能研究3．利用1，3．丙磺酸内酯对nano．Ti02进行表面修饰并与预交联的PVA溶液共混成膜。应用红外(FT-IR)，热重(TGA)和元素分析的表征表明1，3一丙磺酸内酯成功的接枝在nano．Ti02表面。利用XRD，SEM，TEM，TGA，元素分析，机械性能测试以及耐碱性测试对杂化膜的基本性能和结构进行了表征。应用NaOH／Na2W04体系扩散渗析实验模拟了其在回收碱中的分离性能。结果表明磺化nano．Ti02较未修饰前在PVA基体中分散性良好，表面磺化nano．Ti02的加入能够提高扩散渗析过程中OH。的渗析系数以及膜的选择性，但杂化膜的机械稳定性及耐碱性稍有下降。进一步研究表明，当磺化nano．Ti02添加量为3％时膜的综合性能最好，室温下的OH’渗析系数为0．0222m／h，分离系数为32．7。表面磺化的nano．Ti02的引入能够提高膜的离子通量，一方面由于引入了可交换基团磺酸基，提高了Na+的传递速率，PVA本身的羟基与OH。之间通过氢键作用可形成OH’传递的辅助通道，因此膜的离子通量增加；另一方面是由于纳米颗粒表面接枝磺酸基后亲水性提高，与PVA之间的相互作用可以显著提高nano．Ti02与聚合物基体之间的界面相容性，增加膜的致密度，阻碍了W042‘离子的传递，提高了膜的选择性。关键词：杂化膜nano．Ti02扩散渗析碱回收表面磺化万方数据A1bstractAbstractOrganic-inorganichybridmembraneshavefavorableapplicationprospectinthediffusiondialysisprocessbecauseoftheiroutstandingstrength，flexibility,thermalandchemicalstabilityaswellastheothercombinationpropertiescomparedwiththesingle．-componentmembranes．Inthisarticle，poly(vinylalcoh01)(PVA)andnano·-Ti02wereincorporatedtoprepareaseriesofPVA／nano-·Ti02hybridmembranesbyblendingthetwocomponentdirectly．Theas-preparedmembraneswereusedforalkalirecoveryfromNaOI-I／Na2W04mixturebydiffusiondialysissuccessfullyandtherelationshipbetweenstructureofmembranesandseparationefficiencywasdetectedsystematically．Thearticlewasstatedasfollows：1．Originalnano·-Zi02andpre--crosslinkedPVAsolutionwereusedtopreparedmembraneandtheoptimummembrane．-formingconditionswereselectedreferringtotheresultsofdiffusiondialysis．Atfirst，wecarriedoutexperimentsandobtaintheoptimumthermaltreatmenttemperature(130。C)．ThenPVA／nano．-Yi02hybridmembraneswerepreparedwiththemassfractionofnano—Zi02toPVAwere0，1％，2％，3％，4％and5％underthismembraneformationcondition，respectively．XRD，SEM，TEM，TGA，mechanicaltest．，wateruptake(WR)andalkalidurabilitytestswerecarriedouttostudythestructureandpropertiesofhybridmembranes．SeparationefficiencywasdetectedbythesystemofNaOH／Na2W04throughdiffusiondialysisprocess．Theresultsshowedthatadditionofnano·-Yi02improvedthemembranepropertieseffectively,includingthermalstability,mechanica