可渗透反应墙处理酸性矿山废水实验分析-experimental analysis on treatment of acidic mine wastewater by permeable reactive wall.docxVIP
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加均会提高重金属的去除率。实验得到当赤泥在反应柱 上层,锰砂和沸石在反应柱下层对重金属的去处效果较好。最后,实验论证了赤泥、锰砂和沸石作可渗透反应 墙的墙体材料处理 AMD 的可行性。PRB 技术非常经济和实用是适合我国国情的处理地下水的新技术。关键词:可渗透反应墙;酸性矿山废水;赤泥;锰砂;重金属Treatment of Acid Mine Drainage with Permeable Reactive Barrier: An Experimental StudyAbstractPermeable Reactive Barrier is a passive treatment technology which has generally been used to treat low flow and/or low contaminant loads of acid mine drainage. The AMD with higher heavy metals and lower pH was produced in mining process. Red mud is waste which was produced in alumina production. This study simulated PRB to treat AMD in lab. The experiment used red mud, manganese sand and Clinoptilolite as reactive material. The AMD was configured in experiment. The red mud was fed from the alumina company of Guizhou managne sand and clinoptilolite were provided by the Keyuan water treatment material company of Henan. The red mud with much alkali and the alkali release slowly which had good adsorption capacity for heavy metals is a fine material to treat AMD. The MnO2 which was contained in manganese sand could treat Mn very well. The adsorption and ion-change action of the clinoptilolite could treat heavy metals very well.The experiment included preliminary experiment and formal experiment. The preliminary experiment designed six columns: A: red mud from Bayer process B: red mudfrom sintering process C: red mud from Bayer process with 400 ℃ cauterize modification;D: red mud from sintering process with 400 ℃ cauterize modification ; E: red mud from Bayer process with 600 ℃ cauterize modification; F: red mud from sintering process with600 ℃ cauterize modification.The parameter of the configured AMD is Fe3+ 56.66 mg/L,Mn2+ 9.34 mg/L, Cu2+ 12.77 mg/L, Zn2+ 7.51 mg/L, Pb2+ 1.12 mg/L, Cd2+ 0.90 mg/L,pH 3.27,EC 3.24 ms/cm. The experiment was carried 15 d.and effluent water used ICP-AAS to measure heavy metals The max Mn2+ and Zn2+ in column A were 0.28 mg/L and 0.12 mg/L respectively. The other heavy metals were unable to detect by
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