锂电池正极材料lini23mn13o2的制备和表征-preparation and characterization of lini 23 mn 13 o 2 cathode material for lithium batteries.docx

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锂电池正极材料lini23mn13o2的制备和表征-preparation and characterization of lini 23 mn 13 o 2 cathode material for lithium batteries.docx

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锂电池正极材料lini23mn13o2的制备和表征-preparation and characterization of lini 23 mn 13 o 2 cathode material for lithium batteries

AbstractLiNi2/3Mn1/3O2isoneattractivesubstitutematerialforLiCoO2duetoitslowcost,bettersafetyandenvironmentalfriendliness.Inthisdissertation,twosynthesismethodsofLiNi2/3Mn1/3O2cathodematerialforhighenergylithiumbatteryhasbeenstudied--polyethyleneglycol(PEG400)assistedsynthesisandoxalateco-precipitation.MaterialcharacterizationmethodsandelectrochemicalperformancetestswereconductedtodeterminethefunctionofPEG400assistedsynthesisandoptimizeoxalatecoprecipitationmethodwhichisofindustrialpotential.InPEG400assistedsynthesis,PEG400wasaddedintotheprecursorsandoxalatemixture,andsinteredat800℃togetLiNi2/3Mn1/3O2material.TheresultsshowedthatthissynthesismethodcaneffectivelyimprovetheperformanceofLiNi2/3Mn1/3O2.Thestructureandmorphologyofas-preparedsampleswereexaminedbyXRD,XRDrefinementandSEM.ItisfoundthatascomparedtobareLiNi2/3Mn1/3O2,thePEG400treatedsamplehasbetterLi/Niorderandenhancedcrystallinitywithmoreuniformparticlesizedistribution.Electrochemicalperformanceoffirstdischargecapacity,50cyclesperformanceandratecapabilityhavebeenstudied.SamplePEG10deliveredaninitialdischargecapacityof172mAhg?1witha0.1Ccurrentbetween2.7-4.5V,whereassamplewithoutPEG400treatmentgaveonlyacapacityof115mAhg?1.PEG10deliveredacapacityof111mAhg?1with1Ccurrent,whilesamplewithoutPEG400treatmentonlygaveacapacityof27mAhg?1.ThisimprovementispossiblyduetotheenhancedcrystallinityandhigherLi/NiorderintheLiNi2/3Mn1/3O2structure.Astooxalateco-precipitation,thepHvalueandprecursorconcentrationhasbeenoptimizedfortheprecipitatesolutionwithtwocontrastexperiments.Theas-preparedLiNi2/3Mn1/3O2materialischaracterizedbyXRDandSEMtostudythestructureandmorphology,whichisfollowedbyelectrochemicaltests.TheresultsshowedthatpH=2ismostfavorableforpreparingLiNi2/3Mn1/3O2withhighcrystallinityandsmallaverageparticlesize,thusleadingtoexcellentelectrochemicalperformance;aprecursorconcentrationof0.12mol/LismostfavorableforpreparingLiNi2/3Mn1/3O2withhighcrystallinity,resultinginbetterelectrochemicalproperties.Keywords:lithiumbatterycath