锂离子电池硅石墨碳负极材料量化制备及电化学性能分析-quantitative preparation and electrochemical performance analysis of silicon graphite carbon anode materials for lithium ion batteries.docxVIP

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锂离子电池硅石墨碳负极材料量化制备及电化学性能分析-quantitative preparation and electrochemical performance analysis of silicon graphite carbon anode materials for lithium ion batteries.docx

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锂离子电池硅石墨碳负极材料量化制备及电化学性能分析-quantitative preparation and electrochemical performance analysis of silicon graphite carbon anode materials for lithium ion batteries

AbstractAsakindofanodematerialoflithium-ionbattery,siliconwillbewildlyutilizedbyitshighspecificcapacity.However,ahighvolumeexpansioncanhaveaseriousimpactonthecyclestabilityofthesiliconmaterialwhilethesiliconandlithiumarealloying/de-alloying.Therefore,thesiliconanodematerialisnotpractical.Thisdissertationsummarizestherecentresearchesandtheindustrializationofsilicon-basedanodematerial.Inthisdissertation,anoptimizedcraftofsintering100gmoreSi/Graphite/Ccompositeisstudiedfortheenlargementofthematerialmanufacture.Basedonmaterialsobtained,thenegativeplatecraftandthedesignparametersofhigh-capacitybatteryarestudiedanoptimizedviaphysicalandelectrochemicalmeasurements.Asuitablerangeforsinteringmaterialandawellargonflowwereoptimizedthroughresearchingforthetemperaturefieldoftubefurnaceheatingzone.Undertheseconditions,100gSi/Graphite/Cmaterialwassintered,whichhadfineelectrochemicalpropertyandbatchesstability.Thematerialshowedainitialcoulombicefficiencyof85%,areversiblespecificcapacityof664mAhg-1after60cycles,aretentionrateof70%andarelativerangebetweenbatchesof12%for4batchesintheirinitialreversiblespecificcapacity.Thematerialobtainedwasusedastheactivesubstanceofanodeandthenegativefoilprocesswasstudiedandoptimizedfromfourfactorsasfollowed,anodecoatingthickness,charge-dischargesystem,heattreatmentandelectrolyteadditives.Thebatterycyclestabilitywasimprovedunderachangedcharge-dischargesysteminthefirsttwocycles,whichshowedainitialreversiblespecificcapacityof1038mAhg-1,areversiblespecificcapacityof796mAhg-1after30cyclesandaretentionrateof77%.Forthickanodeplates,heattreatmentenhancedtheircyclestability.After6hheattreatment,anodeplateswith3mgmaterialshowedareversiblespecificcapacityof548mAhg-1after45cyclesandaretentionrateof85%.Vinylenecarbonatejoinedonlyimprovedthecyclestabilityalittlebutdecreasedthereversiblespecificcapacityalot.Thedesignparametersofhigh-capacityLiCoO2-Si/graphite/C523450lithium-ionbatterywerestudiedandoptimized.Thehighcapacitybatteriesshowedainitialreversiblecapacityof