锂离子电池用pvc改性聚合物电纺膜的制备及性能分析-preparation and performance analysis of pvc modified polymer electrospinning membrane for lithium ion batteries.docxVIP

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锂离子电池用pvc改性聚合物电纺膜的制备及性能分析-preparation and performance analysis of pvc modified polymer electrospinning membrane for lithium ion batteries.docx

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锂离子电池用pvc改性聚合物电纺膜的制备及性能分析-preparation and performance analysis of pvc modified polymer electrospinning membrane for lithium ion batteries

AbstractRecently,polymerlithium-ionbatteriespreparedwithpolymerelectrolytes(PEs)havedrawnthegeneralattentionofmanyresearchers.ThePEshaveseveraladvantagesoverthetraditionalliquidelectrolyte.Theseadvantagesincludesuchasnointernalshorting,leakageofelectrolytesandnon-combustiblereactionproductsattheelectrodesurfaceandsoon.TheseadvantagesofthePEsgreatlyimprovedtheperformanceofpolymerlithium-ionbatteries.SothePEsbecomeanimportantresearchcontentinpolymerlithium-ionbatteries.ThePEsshouldpossessfavorableelectrochemicalperformanceandexcellentmechanicalstrengthatthesametimeintheirpracticalapplication.Butuntilnow,thePEswhichhavegoodelectrochemicalperformanceandmechanicalpropertiesarefew.TheworkisstartedfromthegoodelectrochemicalperformanceandmechanicalpropertiesofthePEs,PVDF、PANandPMMAwhichhavegoodelectrochemicalperformancearechoseasthemainmatrices,theamorphousPVCwithgoodmechanicalstiffenerisblendedtomodifytheirperformance.Theresearchcontentismainlydividedintothefollowingthreeaspects:PVDFwaschosenasthemainmatrix,PVCwasaddedtomodifyitsperformancethroughblending.WehavemadeuseofelectrospinningtopreparePVDF/PVCcompositefibrousmembranes,thecharacterizationandelectrochemicalperformancesoftheelectrospunPVDF/PVCfibrousmembraneswereinvestigated.TheresultsshowedthattheappropriateadditionofPVCeffectivelydecreasedthecrystallinityofPVDFandimprovedtheionicconductivity.WhenthequalityratioofPVDFandPVCwas8:2,thePEshadthelowercrystallinity、thehigheruptakeandionicconductivity(2.25×10-3Scm-1).TheelectrochemicalstabilitywindowofthePEsbasedonPVDF/PVC(8:2,w/w)reached5.1VversusLi.Li/LiFePO4cellbasedonPVDF/PVC(8:2,w/w)PEsshowedafirstdischargecapacityof145.1mAhg-1at0.1C-rateandexhibitedgoodcycleperformance.PANwaschosenasthemainmatrix,PVCwasaddedtoPANtomodifyitsperformancethroughblending.PAN/PVCcompositefibrousmembraneswerepreparedbyelectrospinning,thecharacterizationandelectrochemicalperformancesoftheelectrospunPAN/PVCcompositefibrousmembraneswereinvestigated.TheresultsshowedthattheadditionofPVCincrease