锂离子电池负极材料li4ti5o12和li2ti3o7的制备及电化学性能分析-preparation and electrochemical performance analysis of lithium ion battery cathode materials li 4ti5 o12 and li 2ti3 o7.docxVIP
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锂离子电池负极材料li4ti5o12和li2ti3o7的制备及电化学性能分析-preparation and electrochemical performance analysis of lithium ion battery cathode materials li 4ti5 o12 and li 2ti3 o7
samplessinteredattheairconditionandN2conditionexhibitedtheinitialchargecapacitiesof145.73mAhg-1and132.94mAhg-1,respectively.TheLi2Ti3O7/CanodematerialhadbeenfirstlypreparedviamicrowavemethodusingrutileTiO2and0.38LiOH·H2O-0.62LiNO3astherawmaterials.Theinfluenceofmicrowavepowerandtreatmenttimeonthestructures,morphologiesandelectrochemicalperformancesoftheas-preparedsampleswereobviousbecauseofthemicrowaveheatingisuniformandinstantaneous.TheLi2Ti3O7/Canodematerialsviamicrowaveheatingat640Wfor20minhasthebestelectrochemical.Attherateof0.2C、1C、3Cand5C,theinitialchargecapacitiesofthesamplewere145.68mAhg-1、132.78mAhg-1、112.78mAhg-1and102.73mAhg-1,respectively.KEYWORDS:Lithiumionbatteries,lithiumtitanate,moltensalt,microwavemethod,sol-gelmethod目录目录...................................................................................................................4第一章绪论..............................................................................................................11.1锂离子电池简介...........................................................................................11.2锂离子电池组成及特点.................................................................................21.2.1正极材料............................................................................................31.2.2负极材料............................................................................................41.2.3隔膜材料............................................................................................41.2.4电解液................................................................................................51.3锂离子电池工作原理及特点..........................................................................51.4锂离子电池负极材料的研究进展....................................................................71.4.1碳素负极材料......................................................................................71.4.2硅及硅化物.......................................................................................101.4.3锡基材料..............................
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