两种janus粒子的制备及其性能的分析-preparation and performance analysis of two janus particles.docxVIP

两种 Janus 粒子的制备及其性能研究中文摘要Janus 粒子是近年发展起来的一种具有独特性质的粒子，粒子的两个不同的面上 物理或化学性质不同。由于 Janus 粒子的这种特性，使其在界面修饰、表面活性剂、 自组装、形成 pickering 乳液和电子纸等领域有着广泛的应用前景。首先，本文用溶胀相分离的方法，以聚苯乙烯(PS)单凹陷的粒子为种子粒子，以 氯甲基苯乙烯(VBC)为溶胀单体，利用溶胀相分离方法进行溶胀，得到了球形的 PS/PVBC 粒子。红外和能谱分析结果，证明了粒子为 Janus 粒子。将粒子溶于二甲基 甲酰胺(DMF)中，通过超声离心得到了“月牙形”的粒子。另外，将粒子与硫代葡萄 糖酸钠反应后，通过红外分析得到粒子成功的接上硫代葡萄糖酸钠。再将反应后的粒 子在缓冲溶液中与含有荧光的刀豆蛋白 A 进行吸附实验，在荧光显微镜下观察发现， 粒子的一面有荧光另一面没有荧光，说明粒子与刀豆蛋白 A 进行特异性吸附。其次，本文还介绍了利用简易的微流体 T 型通道制备出了含有磁性粒子的聚乙二 醇二丙烯酸酯（PEG-DA）Janus 粒子，并研究了磁性粒子的大小、液滴在固化前停 留在磁场的时间长短对合成的微米级粒子的影响。我们将 0.699μm 的核壳式聚苯乙烯 磁性粒子分散在分散相中，当液滴固化前在磁场中停留 2 min 或以上的时间时可以得 到较为理想的圆球形的 Janus 微米粒子，我们还观察到 Janus 粒子中的磁性粒子呈线 性排列。关键词：Janus 粒子；溶胀；“月牙型”粒子；蛋白质吸附；微流体；磁性响应作者：王曼 指导教师：张泽新Preparations and Properties of Two Kinds of Janus ParticlesAbstractJanus particles have anisotropic structures and properties in their different sides have attracted considerable attention. The particles have tremendous potential in the fields of materials and engineering such as interface modification, surfactant, self-assembling, forming Pickering emulsions and e-paper.First, the Poly Styrene (PS) dimple spheres can be swollen by vinyl benzyl chloride (VBC) to form spherical particles. The IR and SEM were used to analysis the infrared and surface morphology properties of the particles, respectively. These proved that the particles we synthesized are Janus particles. The particles dispersed in Dimethyl Formamide (DMF) were vibrated by ultrasonic and centrifuged, a kind of moon-like PVBC particles were synthesized.The analysing results of the IR and EDS show that the sulfur group of 1-Thio-β-D-glucose sodium salt reacted with the Janus particles. The FITC-Con A dissolved in buffer solution was adsorbed specifically onto the particles. Fluorescence microscopy image illustrated that one side of the particles had fluorescent and the other side didn’t. This result shows that the particles have specific adsorption properties to protein.Second, a simple T-junction micro-fluidic channel was used in th