la1xcexmn1ybiyo3系列钙钛矿型催化剂对柴油机颗粒物净化性能分析-analysis of purification performance of la 1 xce xm n1 yb iyo 3 series perovskite catalyst on diesel engine particulate matter.docxVIP

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la1xcexmn1ybiyo3系列钙钛矿型催化剂对柴油机颗粒物净化性能分析-analysis of purification performance of la 1 xce xm n1 yb iyo 3 series perovskite catalyst on diesel engine particulate matter.docx

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la1xcexmn1ybiyo3系列钙钛矿型催化剂对柴油机颗粒物净化性能分析-analysis of purification performance of la 1 xce xm n1 yb iyo 3 series perovskite catalyst on diesel engine particulate matter

ABSTRACTThewidely-useddieselengineshavebroughtlotsofbenefitsinpeople’sworkandlife,however,largeamountsofPMandNOxemittedhavecausedseriousdamagestotheenvironmentandpeople.Asakindofcheapandefficientmethod,after-treatmenttechnologyhasgainedinternationalinterests,andmuchemphasisisputonthedevelopmentofhighlyeffectivecatalysts.Inthiswork,seriesofexperimentswereperformedtorevealthereactionmechanismforPM-NOxremovaloverperovskitecatalysts.Themainconclusionsobtainedareasfollows:Ce-substitutionatA-site:DuetothepoorsolubilityofCenitrates,CeO2wereformedandaccumulatedwithCe-substitutionincreasing.ComparedwithLaMnO3,Ce-containedcatalystspossessasmallercrystallinesize,alargerspecificsurfacearea(SSA)andhigherlow-temperaturereducibility.Asaresult,Ce-substitutionleadstoahigheractivityforsootcombustion.Attheatmosphereof10%O2+N2,theLa0.8Ce0.2MnO3samplegivesamaximumsootcombustionratetemperature(Tm)of60?ClowerthanthatoverLaMnO3.Bi-substitutionatB-site:ComparedwithLaMnO3,BisubstitutionatB-siteleadstoasignificantimprovementintheSSA,α-O2amountandlow-temperaturereducibilityofthecatalysts.However,whenthesubstitutionratioofBiexceeds30%,largeamountsofBi0.775La0.225O1.5areformedandaccumulatedoverthesurfaceofthecatalyst,resultinginadecreaseoftheSSA.TGresultsrevealthat:Bisubstitutionenhancesthecatalyticactivityforsootcombustion.LaMn0.7Bi0.3O3possessesthehighestactivity,givingaTmof394?CandΔTof84?C.SimultaneoussubstitutionatA-andB-sites:ComparedwithA-sitesubstitutionorB-sitesubstitution,thesubstitutionatbothA-andB-sitesleadstoahigherSSA,α-O2amountandlow-temperaturereducibilityofthecatalyst.Asaresult,thecatalystpossessesahigheractivityforsootcombustion.Amongthesecatalysts,La0.8Ce0.2Mn0.7Bi0.3O3exhibitsthehighestactivity,givingaTmof385?CandΔTof68?Cintheatmosphereof10%O2+N2.SimultaneoussootandNOxremoval:TheadsorptionofNOxoverperovskitecatalystsconsistsofsurfacephysicaladsorptionandlatticeadsorption.ThefacilereducibilityofB-sitecationsinperovskitescouldeasilyactivatethesurfaceadsorbedoxygen,andtransferitt