胶体导体表面静电作用.pptVIP

Colloidal electrostatic interactions near a conducting surface胶体导体表面的静电作用Marco Polin,1 David G. Grier,1 and Yilong Han21Center for Soft Matter（软物质） Research, New York University, 4 Washington Place, New York, New York 10003, USA2Department of Physics, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong KongReceived 2 May 2006; revised manuscript（手稿修订） received 19 July 2007; published 30 October 2007 Like-charged colloidal spheres dispersed in de-ionized water are supposed to repel each other. Instead, artifact-corrected video microscopy measurements reveal an anomalous long-ranged like-charge attraction in the interparticle pair potential when the spheres are confined to a layer by even a single-charged glass surface. These attractions can be masked by electrostatic repulsions at low ionic strengths. Coating the bounding surfaces with a conducting gold layer suppresses the attraction. These observations suggest a possible mechanism for the anomalous confinement-induced attractions. 带电胶体球分散在去离子水中本应该是相互排斥的,去影修正显微镜显影的检查出现了一种反常的粒子间出现的两极长距离的静电作用，这种静电作用出现在一个被一个单层玻璃包围的球体当中。这种作用被掩盖在低离子强度的相互排斥作用下。将表面一种导电金属层来抑制相互吸引作用。这个理论提出了对不规则的封闭导体内部作用的一种可能的原理。 I. INTRODUCTION The electrostatic interaction between charge-stabilized colloidal particles is mediated and modified by simple ions dissolved in a supporting electrolyte. For like-charged particles, the resulting effective interaction, described by the Poisson-Boltzmann mean- field theory , is predicted to be always purely repulsive independent of the strength of the electrostatic coupling, the valency of the suspended ions, or the state of confinement of the suspension. 静电电荷之间的相互作用，介导的稳定胶体粒子和电解液是作为媒介和重排通过简单的离子溶解。对于类似的带电粒子，由此产生的有效互动，被泊松-波尔兹曼平均场理论所描述，预计总是纯粹独立的静电耦合的强度的，悬浮离子的化合价，暂时紧闭的态。 經典 Poisson-Boltzmann 理論 膠體科學中對靜電力的處理多基於經典的Poisson-Boltzmann 理論，其包含了電學及熱運動的兩個重要結果。 從靜電學來說： 電荷與電位滿足高斯定律，或等效的Poisson 方程。由此方程可以從已知的離子分佈算出電位。從統