二[3,5-二甲基-4-吡唑]甲烷配合物的晶体结构和荧光性质第二配体的影响-influence of second ligand on crystal structure and fluorescence properties of bis [ 3,5 - dimethyl - 4 - pyrazole ] methane complex.docxVIP

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二[3,5-二甲基-4-吡唑]甲烷配合物的晶体结构和荧光性质第二配体的影响-influence of second ligand on crystal structure and fluorescence properties of bis [ 3,5 - dimethyl - 4 - pyrazole ] methane complex.docx

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二[3,5-二甲基-4-吡唑]甲烷配合物的晶体结构和荧光性质第二配体的影响-influence of second ligand on crystal structure and fluorescence properties of bis [ 3,5 - dimethyl - 4 - pyrazole ] methane complex

those in 6 are configured as either cis or trans, of which the cis, combining to Cd2+ ions, furnishes the zigzag chains and the trans, combining to Cd2+ ions, furnishes the helices. With incorporation of Cd2+ into the diversely configured DMPMs and angular IPAs, the ternary polymer gives a binodal (52.62.72)(53.63) topologized net. Indicatively, the first ligands in 7 are all trans-configured, to work together with HBTA, rendering a (4, 4) network. Luminescencespectra of three 2-D complexes suggest that the energies of DMPM-based emissions of them are analogous, but not the widths. A suggestion of the observation is that the photoresponse of DMPM is subject to its coordination manner. What is more, the thermal analysis reveals that the complexes are decomposed in the same way, but different in the desertion temperature of DMPM, based on which we can conclude that the second ligands affect not only the coordination mode of DMPM and assembly of coordination polymers, but also their luminosity and thermal property.In chapter 4, four complexes with DMPM as first ligand and pyridine dicarboxylic acids (2,5-pyridine dicarboxylic acid (2,5-PDC), 2,6- pyridine dicarboxylic acid (2,6-PDC)) as second ligands, are demonstrated, of which the [Cd(3-PDC)2(DMPM)]n (8) is 2-D and can be reducedinto a (44, 62) topological network, therein the 2,5-PDC appears as 3-picolinic acid for thedecarboxylation of 2-position and gives the double-stranded helix, in combination to Cd2+. Instead, the [Zn(2,5-PDC)(DMPM)]n (9) constructs as a 1-D triple strand. In another comparison, the Cl-involving [Cd2(2,6-PDC)(μ2-Cl)(Cl)(DMPM)·H2O]n (10) configures as a 2-D networkpresenting a (42.62)2(42.62.82) topology, in contrast to the I-involving [Cd2(2,6-PDC)I2(DMPM)]n(11), as a grid-like network. Fluorescence of 8 and 10 indicates that the photoresponses of two compounds are comparable, meaning that the position-isomeric second ligands not significantly affect the bulk photobehavior of the complexes.Ke