反应烧结注浆氮化硅陶瓷材料的制备与性能分析-preparation and performance analysis of reaction sintering grouting silicon nitride ceramic material.docx

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反应烧结注浆氮化硅陶瓷材料的制备与性能分析-preparation and performance analysis of reaction sintering grouting silicon nitride ceramic material.docx

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反应烧结注浆氮化硅陶瓷材料的制备与性能分析-preparation and performance analysis of reaction sintering grouting silicon nitride ceramic material

Preparationandpropertiesresearchofreaction-bondedgroutingsiliconnitrideAbstractThestudypurposeisceramiccrucible,itisusedtoloadsiliconrawmaterialintheprocessofsolarsiliconingots.Currently,quartzceramicscruciblewithSi3N4coatingisusedintheproduction,itisproposedtomakeoutsiliconnitrideceramiccruciblesdirectlytoreplacetheexistingquartzcruciblesinthisstudy.Combinedwiththeslipcastingmethodandreactionsinteringmethod,itisaimtoachievelow-costpreparationrequirementsofcomplexshapedsiliconnitrideceramicmaterial.Maincontentsandresultsareasfollows:Silicon-basedslurryofhighsolidcontentispreparedusingsiliconastherawmaterial,addingdispersant,binder,sinteringadditives.Studytherheologicalpropertiesofsilicon-basedslurryindifferentsize,differentdispersants,differentpHandfindtheoptimalparameters.IthaseffectonthedensityandporosityofsinteredbodytoincreasedifferentcontentofSi3N4andY2O3.Andtestbendingstrengthandthethermalshockresistanceandfracturetoughnessofsinteredbody.Itisfoundthatthe2ndSi-basedslurry(includingsiliconnitride)hadthebestrheologicalpropertiesinthealkalineenvironment,60%highsolidcontent,63.6cPlowviscosity,dispersed,tomeettherequirementsofgrouting.Dryingshrinkageisverysmallandchangeislessthan5%ofthetotalvolume.Thehighestdensitysinteredbodyisfoundedadding5%Si3N4and2%Y2O3,upto2.30g/cm3.ReactionsinteredSi3N4ofSandPhavebetterdensity,theporosityofSislargethanP,therefore,theflexuralstrengthofPisbetter.Lowporosityisfavorableonthebendingstrength，butforthermalshockresistance,theappropriateporosityisfavorable.ThermalshockresistanceofSisbetterthanP.FoundthatthediscreteoffracturetoughnessofreactionsinteredSi3N4isinaccordancewithweibulldistribution,throughstatisticalanalysisofthefracturetoughnessofSandP.ForreactionsinteredSi3N4ofP,theaveragefracturetoughnessupto5.23MPa·m1/2,weibullmodulusupto6.88.Keywords：Si3N4,Slipcasting,Reactionsintered,Thermalshockresistance,Fracturetoughnes目录1绪论1.1概述·········································································································