废杂铜火法精炼除铅工艺及机理分析-technology and mechanism analysis of removing lead from waste copper by pyrometallurgical refining.docxVIP

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废杂铜火法精炼除铅工艺及机理分析-technology and mechanism analysis of removing lead from waste copper by pyrometallurgical refining.docx

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废杂铜火法精炼除铅工艺及机理分析-technology and mechanism analysis of removing lead from waste copper by pyrometallurgical refining

Abstractfor calculation of lead removal rate, in a certain range could be appropriate adjustment of flux composition. Under different temperature of the activity of lead was calculated, the results turned out that the higher the temperature, the higher the activity of lead, the larger the equilibrium constant, the more unfavorable to lead removal of reaction.Through the analysis of the three kinds of removal lead agent the phosphoric acid, boric acid and silicate type, found that removal lead agent of the phosphate type was the best one, its reaction time was the shortest. Removal lead agent of Boric acid type was also good, with the different composition of flux and the holding time, holding time for 30min, the rate of removal lead was above 80%; removal lead agent of Silicate type was the worst, not only the reaction time is long, and the rate of removal lead was peaked at 50%.Key Words:the secondary copper resources; in addition to the lead oxide; molten salt; FACTSAGE software; the thermodynamic data目录摘要.................................................................................................................................... IAbstract.....................................................................................................................................II目录......................................................................................................................................... IV第一章概述.......................................................................................................................... 11.1 课题背景................................................................................................................... 11.2 废杂铜原料来源 ...................................................................................................... 31.3 铅的危害及废杂铜除铅的目的 ............................................................................. 41.4 废杂铜的除杂机理.............................................................................