分别掺加ag2o b2o3以及b2o3是否预烧对zno系压敏电阻性能的影响-influence of pre-sintering of ag2o3 and b2o3 on zno varistor performance.docxVIP

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分别掺加ag2o b2o3以及b2o3是否预烧对zno系压敏电阻性能的影响-influence of pre-sintering of ag2o3 and b2o3 on zno varistor performance.docx

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分别掺加ag2o b2o3以及b2o3是否预烧对zno系压敏电阻性能的影响-influence of pre-sintering of ag2o3 and b2o3 on zno varistor performance

过程中会熔融，使得晶间液相量增加。不同的作用机理使得这两种掺加物对压敏电阻样品的性能产生了不同的影响。Ag2O 及 B2O3 掺加的样品的微观结构的不同印证了其作用机理的不同。根据电镜观测：掺加 Ag2O 的样品中 ZnO 晶粒体积较小、棱角分明，晶间相分布均匀，掰断试样的断面参差不齐，且有穿晶断裂现象，表明晶粒间的结合力较弱，晶间相与晶粒间的结合力较强；掺加 B2O3 的样品中 ZnO 晶粒体积较大、晶粒边缘圆润，晶间相分布较集中，掰断试样的断面非常平整，表明晶粒间的结合力较强，晶间相与晶粒间的结合力相对较弱。关键词：高压直流；ZnO 压敏电阻；电性能；Ag2O 掺杂；B2O3 掺杂Effect of Ag2O , B2O3 respective addition and pre-heat treatment of B2O3 on the properties of ZnO based varistorsMajor：Materials scienceMaster:Liu Xiangyang Teather：Professor Fan JiweiABSTARCTVaristors all have the function of voltage suppression, they can prevent the damage caused by ESD, surge and other transient current, their application fields covers almost all of electrical-equipment and electronic devices. Compared with other common pressure sensor, ZnO varistors has the clear advantage in non-linear, surge capacity, voltage range, and many other technical parameters. Japan, Russia and the United States all have had the technology to product UHV ZnO surge arrester and varistors with ultrahigh voltage gradient. Among them, Japan has been manufacturing high-end varistors with strong protection property in 2011. Now, advanced core technology of ZnO varistors is monopolized by electric power industry in the developed country, such as Japan. ZnO varistor industry in China has developed for decades, but there are still some gaps with international advanced level.In this article, I added Ag2O and B2O3 in practical formulation respectively, and complemented with advanced burn-in process of adding powder, and at last, I Researched the properties and micro-structure of HDC ZnO Varistors. Research results show that: on the premise of B2O3 powder’s added weight do not exceed 0.12wt%, Ag2O and B2O3 improve the relative density.However, due to the large difference between the ionic radius of B and Ag, mixedwith Ag2O and B2O3 have different effects on other electrical properties of ZnO varistors. The leakage current IL decreases with added of Ag2O, but it increases with added of