纺织品上静电自组装sio2pei薄膜结构生色研究-study on the structure color generation of electrostatic self-assembled sio _ 2 pei film on textiles.docxVIP

纺织品上静电自组装sio2pei薄膜结构生色研究-study on the structure color generation of electrostatic self-assembled sio _ 2 pei film on textiles.docx

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纺织品上静电自组装sio2pei薄膜结构生色研究-study on the structure color generation of electrostatic self-assembled sio _ 2 pei film on textiles

和涤纶纤维表面形态结构和内部微结构及纤维集合体形态结构的差异影响两种纤维/织物表面SiO2/PEI薄膜的选择性相长干涉光,以致蚕丝织物结构色的鲜艳度、亮度和虹彩效应不及涤纶织物结构色。关键词:薄膜干涉,结构色,静电自组装,SiO2纳米粒子,纺织品iiAbstractTextilecolorationistraditionallyachievedbymeansofusingchemicalcolorantssuchasdyesandpigments.However,theformationofstructuralcolordoesnotrequireanychemicalcolorants,andthetypicalpropertiesofstructuralcolorsarehighbrightness,highsaturation,iridescenteffectandwithoutfading,etc.Inthispaper,thethinfilmswithstructuralcolorwerefabricatedontextilesbyelectrostaticself-assemblyapproach.Theassemblyconditionsofdifferentfabrics,themorphologyandopticalpropertyofSiO2/PEIthinfilm,thefactorsofinfluencingonstructuralcolors,themechanismgeneratingstructuralcolorsandtheassemblyprocessofSiO2/PEIthinfilmwithstructuralcolorwereinvestigated.Itwasbelievedthatthisstudycouldoffersomevaluableguidanceindevelopingtextileeco-colorationtechnology.Themajorworkcouldbesummarizedasfollows:1.AssemblyconditionsofSiO2/PEIthinfilmsfabricatedondifferentfabrics:polyesterfabricandsilkfabricwerechosenasmatrixmaterials,andtheeffectsoftheirsurfacemorphologyandphysicochemicalpropertiesonthefabricationofSiO2/PEIthinfilmswereinvestigated.TheappropriateassemblyconditionsfordifferentfabricswereoptimizedbyevaluatingthedistributionofSiO2nanoparticlesonfibersurface.2.FabricationofSiO2/PEIthinfilmandtheinfluenceonopticalpropertyandstructuralcolorofSiO2/PEIthinfilm:SiO2nanoparticlesandpolyethyleneimine(PEI)polyelectrolytewerealternatelyfabricatedondifferentfabrics,andthestructuralcolorsoffabricscoatedwithSiO2/PEIthinfilmwereinvestigatedthroughthecolor-photoscapturedbyadigitalcamera,andalsothroughthereflectancespectraandtheimagesmeasuredbyaDigiEyesystemandamulti-anglespectrophotometer.ThemechanismofstructuralcolorsformationwasstudiedbydiscussingtheeffectofSiO2nanoparticlesize,assemblycyclenumberandviewingangleonstructuralcolorsandanalyzingthemorphologyofSiO2/PEIthinfilm.3.MorphologyandassemblyprocessofSiO2/PEIthinfilmassembledindifferentcycles:thedistributionofSiO2nanoparticlesiniiiSiO2/PEIt

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