改性活性炭对水中246 tcp的吸附及微波再生的实验研究-experimental study on adsorption and microwave regeneration of 246 tcp by modified activated carbon in water.docxVIP
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改性活性炭对水中246 tcp的吸附及微波再生的实验研究-experimental study on adsorption and microwave regeneration of 246 tcp by modified activated carbon in water
、喇喇AMMm川川nwu川川川吨,但恻恻唰内,h唰唰唰A呻唰川州hum川川鸣,h州州VE摘要氯盼类有机物质种类繁多,是一樊典型的水体三致污染物,其降解及消除…直备受关注,采用活性炭吸附法去除氯盼物质…直是人们研究的热点。微波由于其具有加热速度快,选择性强等优点,近年来广泛应用于活性炭的再生工艺。本文以2,4,6-TCP为研究对象,对水中2,4,6-TCP在铁锤改性活性炭柱上的穿透特性及吸附饱和活性炭的微波再生进行了研究。研究结果如下:1、铁锤改性活性炭对水中低浓度2,4,6-TCP的动态吸附效果较好,用Yoon-Nelson模型对实验数据进行拟合,重合性很好,说明Yoon-Nelson模型能够较为准确地预测2,4,丁CP溶液在改性活性炭柱上穿透特性。2、活性炭性进水流量越大,穿透曲线就越陡,到达吸附穿透点的时间也越早。对不间流盘下得出的穿透曲线用Yoon-Nelson模型进行数值模拟,计算结果与实验结果符合较好,ln[ClCo-Ca与t都保持着良好的线性关系,相关系数R2均在0.9以上。流量对Yoon-Nelson模型各参数的影响分别为:T值随着进水流量的增加而降低,而k值则升高。K与流量呈线性关系,而丁、tl,但与流量之间呈现幕函数关系。3、微披功率,微波辐照时间,活性炭装填量都会对再生产生影响,正交实验表明,各因素对微波再生的影响程度大小依次是:微波功率,微波辐照时间,括性炭装填量,微波辐照再生载2,4,6-丁CP活性炭的最优条件是:微波功率450w,微波辐照时间6m恤,活性炭装填最为址。4、通过六次重复吸附/再生实验,比较了再生前后活性炭的吸附性能,结果显示,再生一次后的活性炭对2,4,6-丁CP的吸附能力优于原炭,再生二次和六次后的活性炭的吸附性能虽有所降低,但还是有比较好的吸附效果。5、经过多次微波再生以后的活性炭,不仅能维持较好的吸附性能,炭损耗率也较低,活性炭经六次再生后,总的损耗事仅为5.45%。可见,微波再生活性炭无论在技术上还是经济上都是可行的。关键词:2,4,ιTCP;铁锚改性活性炭:动态吸附;Yoon户Nelson模型:微波再生AbstractCh1orophenolsorganiccompounds,withgre础varieties,缸etypicalcontaminantscausingw旧时tobecarcinogenic,inducingmalformationandmutation.丁hedegradationandeliminationofCh1orophenolsarealwayscatchingresearchersattention,andactivatedcarbonadsorptionmethodforremovalofch1orophenolssubstanceshasbeentheh创topicofresearch.Microwave,duetoitsfastheatingspeed,highselectivityandotheradvantages,iswidelyusedinactivatedcarbonregenerationprocess.2,4,6-TCPisresearchedin也ispaper,andthedynamiccharacteristicsofactivatedcarbonmodifiedbyFeandMntoadsorb2,4,6-TCPandmicrowaveregenerationoftheadsorptivesaturatedactivatedcarbonarestudied.Theresultsare创follows:1、UseactivatedcarbonmodifiedbyFeandMntotre剧由ewaterwithlowconcentrationof2,4,6-TCP,世ledynamicadsorptioneffectisgood.ηleexperimentaldataarewellfittedwithYoon唰Nelsonmodel,therefore,Yoon翩Nelsonmodelcanwellpredictthebreakcharacteristicsof2,4,6-TCPsolutiononmodifiedactivatedcarboncolumn.2、Wehnt10wislarger,breakthroughcurveismoresteep,andadsorptionbreakthroughpointreachesinearliertime.UseYoon?Nelsonmodeltosimulatethebreak由roughcurvesunderdifferentt10wrates,theca1culationre
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