改性硅藻土吸附重金属铅锌的实验分析-experimental analysis on adsorption of heavy metal pb and zn by modified diatomite.docxVIP

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改性硅藻土吸附重金属铅锌的实验分析-experimental analysis on adsorption of heavy metal pb and zn by modified diatomite.docx

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改性硅藻土吸附重金属铅锌的实验分析-experimental analysis on adsorption of heavy metal pb and zn by modified diatomite

AbstractInthispaperweadoptdiatomiteformatrix,anduescalciumcarbonateandmanganeseoxidetomodifiedthesurfaceofdiatomiteparcles,comparativestudyontheadsorbenteffecteofdiatomiteandmodifieddiatomiteadsorptionPb2+andZn2+.UseBathexperimentstostudymodifieddiatomiteadsorptionofPb2+、Zn2+andCd2+fromaqueoussolutions.Theadsorptionisotherm,adsorptionkineticsandadsorptionthermodynamicspropertiesofcalciumcarbonateandmanganeseoxidemodifieddiatomitewithPb2+andZn2+andtheinfluenceofsifferentmediaonadsorptionwerestudied.Theresultsshowedthat:SEM,FT-IRandXRDwereshowedthatmodifiedparticlesandthediatomsurfaceormationofadsorptionnetworksandmoreporous,andhavealotofslugandflakydepositsandmesoporouseffect.Newabsorptionpeakofcalciumcarbonateappeared,absorptionpeakoffreehydroxylO–Hdisappearedaftermanganeseoxidemodified.thediffractionpeakintensityofSiO2reduction,themodifieddiatomandmodifiedcompoundsbondedtoeachother,andformationofacertaindependentinterfacialeffects,andthespecificsurfaceareaincreased.CalciumcarbonateandmanganeseoxidesmodifieddiatomiteadsorptionPb2+andZn2+.Withtheincrementofthesorbentdosagetheremoveratewasenhancedandtheadsorptioncapactiywasdecrease,whenthedosagewas1g/L,thePb2+removalratewas99.94%and97.50%,theadsorptioncapacityof92.70mg/gand94.73mg/g,respectively.Whenthedosagewas3g/L,thePb2+removalratewas78.45%and80.40%,theadsorptioncapacityof25.14mg/gand25.78mg/g,respectively.WiththeincresseofpH,theremoverateandtheadsorptioncapactiywasenhanced.WhenthepHwas5,thePb2+removalratewas99.42%and96.55%,theadsorptioncapacityof95.15mg/gand92.7mg/g,respectively.WhenthepHwas7,theZn2+removalratewas50.11%and50.65%,theadsorptioncapacityof48.23mg/gand48.75mg/g,respectively.Withtheincrementoftheinitialconcentrationtheremoveratewasdecreaseandtheadsorptioncapactiywasdecrease.WhentheinitialconcentrationofPb2+andZn2+was500mg/Land400mg/L,respectively.theremovalratewas46.38%and22.15%、36.40%and17.66%，theadsorptioncapacityof211.50mg/gand88.59mg/g、166.01mg/gand70.42mg/g,respectively.Studiesonisothermalabsorptio