改性季铵盐从高碱度溶液中萃取钒的分析-analysis of extraction of vanadium from high alkalinity solution by modified quaternary ammonium salt.docxVIP

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改性季铵盐从高碱度溶液中萃取钒的分析-analysis of extraction of vanadium from high alkalinity solution by modified quaternary ammonium salt.docx

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改性季铵盐从高碱度溶液中萃取钒的分析-analysis of extraction of vanadium from high alkalinity solution by modified quaternary ammonium salt

AbstractBauxitecontainingvaryingdegreesofV2O5,whichcanbeusedastheresourcesofvanadiumextraction,andvanadiuminaluminaproductionprocesseshaveagreatimpactonthequalityofthealuminaproducts.Inviewoftheharmofvanadiuminaluminaproductionprocessesandtheexistingrecyclingprocessessuchascrystallizationmethodandionexchangemethodwiththeproblemsoflongprocess,highenergyconsumption,lowrecyclingrate,thispaperputforwardanewprocesswhichincludingthematerialliquidwithouttreatment,thedirectsolventextractionofvanadiumfromhighalkalinesolutionofaluminaspentliquorusingquaternaryammoniumsaltasextractantandraffinatedirectlyreturnedtotheleachingprocess.Inthispaper,solventextractionofvanadiumfromhighalkalinesolutionwiththemodifiedquaternaryammoniumsaltwasstudied.Anditwasmainlyinvestigatedseparatelyfromthescreeningandtransformationofextractants,theinfluencefactorsofextractionandstrippingandthemechanismofextractionvanadium.Itcouldbesomereferencevalueonthesolventextractionofthevanadiumfromaluminaproductionprocess.VarioustypesextractantswereusedintheextractionvanadiumfromhighalkalinesolutionsandtheresultsshowedthattheextractionperformanceofCO32-typequaternaryammoniumsaltTOMACwassignificantlybetterthantheHCO3-,SO42-andCl-type2-quaternaryammoniumsaltTOMAC,sotheCO3typequaternaryammoniumsaltTOMACwasdeterminedasextractant.StudyonthetransformationprocessesofCl-typequaternaryammoniumsaltTOMACwerecarriedout.ThetimesrequiredforeachstepinthetransformationprocesswereidentifiedbydeterminingtheconcentrationofCl-,SO42-,CO32-anionexchangeintreatedsolutiontocalculatetheexchangeequilibriumrateandanalysingtheinfraredspectraofextractantsaroundthetransformationprocess.Experimentalresultsshowedthatundertheconditionof2/1fortheorganicphaseratio(O/A),25℃forthetemperature,1hourforshakingtime,SO42-typequaternaryammoniumsaltcouldbeobtainedaftertheCl-typequaternaryammoniumsalttreatingby3mol/Lforsulfuricacidfor7times,thenthroughwashingtheorganicphaseby2mol/Lforsodiumhydratefor2timesandtreatingby1mol/Lforsodiumhydrogencarbonatefor5