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改性聚乙烯醇新型纺丝工艺分析-analysis of new spinning process of modified polyvinyl alcohol
STUDYONMODIFIEDPOLY(VINYLALCOHOL)FIBERSPREPAREDBYANEWKINDOFSPINNINGAbstractPoly(vinylalcohol)isamulti-hydroxylpolymerwithexcellentmechanicalproperties,thermalproperties,moistureabsorption,corrosionresistance,weatherresistanceandinterfacialbondingproperties,whichistherawmaterialofvinylon.However,themulti-hydroxylsofPVAmakeitsmeltingpointclosetoitsdecompositiontemperature.AsaresultthethermalprocessingofPVAisdifficult.SoPVAfibersareusuallypreparedbywetspinning.However,thecomplicatedprocessing,heavypollutionandpoormechanicalpropertiesofwetspinninglimitPVAfibersapplications.Therefore,ithasgreattheoreticalandsocio-economicvaluestoexploreanewgreenspinningprocessandpreparinghigh-performancePVAfibers.Inthispaper,ametalioncomplexingagentM,environmentallyfriendlyplasticizerAandpolyetherplasticizerBformedacompoundmodifier.IaddedittorawPVAtopreparemodifiedPVA.ByFTIR,DTA-TGandXRD,thispaperstudiedtheeffectsofdifferentcontentsofmodifieronhydrogenbonding,thermalpropertiesandcrystallizationofmodifiedPVA.Bycapillaryrheometer,thispaperstudiedtheeffectsofdifferentcontentsofeachmodifier,processingtemperatureandshearrateontherheologicalbehaviorofmodifiedPVA.IspunbelowthemeltingpointofthemodifiedPVA,whichiscalledquasi-melt-spinningprocess.Bypolarizingfiberscope,FTIR,XRD,DTA-TG,Istudiedthesurfacemorphologyofas-quasi-melt-spunfibersofmodifiedPVA,changesofhydrogenbonds,crystallizationandthermalproperties.Byadraftingequipment,Istudiedtheeffectsofdrawingtemperature,drawingspeedandthecontentofmetalioncomplexingagentMonbreakingelongationofmodifiedIIIPVAfibers,andthusgotthebestparametersofdrawingprocess.Theresultsshowthat:addingametalioncomplexingagentscanimprovethethermalstabilityoftheM-modifiedPVA,lowerthemeltingpoint.Itisnotcontributetothespinningprocess,butit’sadvantageousinsuppressingthermaldegradationindrawingprocess,andthusimprovingthefinalmechanicalpropertiesoffibers;AddingenvironmentallyfriendlyplasticizerAandalittlepolyetherplasticizerBcanimprovethefluidityandspinnabilityofthemodifiedPVA
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