高温高压下二元气体扩散系数激光测试系统与仿真-laser measurement system and simulation of binary gas diffusion coefficient at high temperature and pressure.docxVIP
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高温高压下二元气体扩散系数激光测试系统与仿真-laser measurement system and simulation of binary gas diffusion coefficient at high temperature and pressure
AbstractNowadays,withstrictenvironmentalprotectionlegislationandtheincreasinglyfiercemarketcompetition,theelectricityproductionalwayssearchesamoreefficientandlowerpollutedwaytousethefuels.Toachievethis,ontheonehand,wecanestablishprecisemathematicalmodelsfornumericalsimulationtoevaluatetheefficiencyofdifferentcoalboilers,ontheotherhand,wecandevelopmoreadvancedtechnology,suchasPFBB、IGCC,whichbothneedsabasicphysicalquantitiesdiffusioncoefficient.Unfortunately,mostofthegasdiffusioncoefficientsweremeasuredatnormaltemperatureandpressure,whichcannotbeusedtoestablishthekineticmodelsofcoalcombustionorgasificationabove1MPa.Measuringgasdiffusioncoefficientsunderhightemperatureandhighpressureissignificantandhelpfulinsovlingthisproblem.Themethodsanddevicesformeasuringthegasdiffusioncoefficientsaresummarizedinthisthesis,andthelargetransverseshearinglaserinterferometrycombinedwiththeimprovedLoschmidtcellwithaballvalvearechoosen.Aexperimentalsystemformeasuringgasdiffusioncoeffisionsunderhightemperatureandhighpressurearedesigned.Theeightmajorforeignbinarygasdiffusionmodelsareanalysised,andtheFSGcombinedwithRSPmodelareusedtocalculatethediffusioncoefficientsofbinarysystemsO2-CO2、O2-CO、CO2-CO、O2-CH4、CO-H2athighpressure(0.1-5MPa),hightemperature(lessthan1273K).Thetwo-volumelasershearinginterferometergasdiffusionmodelisestablished.Differentgasesunderdifferentconditionsaresimulatedinmatlab.Withthecenterlinemethodcombinedwiththeminimummean-varianceoptimizationprincipletheimagesoftheinterferencefringesareanalyzed,bywhichthethree-dimensionalconcentrationdistributioninthediffuseprocessisobtainedfurthermore.Theresultsshowthat:theconcentrationerrorsofthelasershearinginterferometerarebellow1.07%;theexperimentsystemwesetuphasagoodperformanceonsealingandrealtimemeasuring.Asthediffusionproceeds,theinterferencefringesfirstgodensityandthengothin.Thedensityofthefringesgothickerwiththepressureincreased.Differentconditionsatdifferenttimes,thefringesonCCDisverycleartodistinguish.Thethreedimensionalconcen
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