有机光电高分子报告.pdfVIP

有機光電高分子報告： 螢光與磷光 許禮璿 邱健華 成柏翰 01/02/2008 Outline • 螢光和磷光的定義與基本物理原理 • Paper (Theory) Doping Energy transfer Singlet fraction χs • Paper (Applications) • 螢光 ： ： The molecular absorption of a photon triggers the emission of The molecular absorption of a photon triggers the emission of another photon with a longer wavelength. another photon with a longer wavelength. Usually the absorbed photon is in the ultraviolet range, and the Usually the absorbed photon is in the ultraviolet range, and the emitted light is in the visible range. emitted light is in the visible range •磷光 ： ： Unlike fluorescence, a phosphorescent material does not Unlike fluorescence, a phosphorescent material does not immediately re-emit the radiation it absorbs. immediately re-emit the radiation it absorbs. Phosphorescence lifetimes Fluorescence lifetimes ground state singlet triplet exciton S Exciton T 螢光 磷光 Triplet state 能量比 singlet state 低 S T T T + - 0 Singlet exciton Intersystem S cros