乙醇、生物甲酯对柴油机性能及排放影响-effect of ethanol and methyl ester on diesel engine performance and emission.docxVIP

increase in the maximum heat release and advance the starting point of combustion. The PAH and thermal NO formation increased with the the increase of unsaturated esters. The prompt NOx formation was also indirectly show increases. The carbon carbon double bonds will cause the CO formation amount reduction, and more likely to be oxidized to CO2. Meanwhile, the formation of formaldehyde in the combustion process will be reduced with the unsaturated ester proportion increased, and the important reactive radical such as OH radical will be promoted with the increase in the proportion of unsaturated ester which accelerated the high temperature reactions. In order to better understand the combustion process of methyl esters and uncovered the effects of ester moiety in methyl esters on the combustion process and and harmful emissions formation, a combined methyl butanoate and a combined n-butane oxidation chemical kinetics model were builded. The PAH and NOx formation reaction mechanism were added to the combined models. The simulation results show that: the ester moiety in methyl esters will change its combustion reaction path and lead to more oxygenated product formation such as CO, CO2, CH2O and so on. The oxygen atoms in the ester moiety will drag one carbon atom from the the carbon pool which could be form PAH precursor and consequently reduce the PAH formation. The ester moiety will increase the local oxygen concentration and correspondently increase the thermal NOx formation which is consistent with experimental results.KEY WORDS：Diesel engine, Methyl ester, Ethanol, Reaction mechanism, Combustion characteristics, Emission characteristics目录第一章 绪论...........................................................................................................11.1 前言..........................................................................................................11.2 乙醇、生物甲酯在柴油机上的应用......................................................11.2.1 乙醇在柴油机上的应用............