新型abc三嵌段液晶共聚物的分解与表征.pdfVIP

湘潭大学硕士学论文 黄孝华 Abstract The literature reporting the recently researches of block copoloymers, especially the rod-coil triblock copolymers were briefly summarized in this dissertation. A series of novel ABC mesogen-jacketed liquid-crystal triblock copolymers with poly{2,5-bis[(4-methoxyphenyl)oxycabony] styrene}(PMPCS) as rod block were designed and synthesized by atom transfer radical polymerization (ATRP) and its phase behavior was discussed. 1. The macromolecular initiators PEO-Br, bromo-terminated PEO was prepared by esterification between PEO and 2-bromoisobutyryl bromide. The ATRP of an amphiphilic diblock copolymer PEO-b-PS was acchived using CuBr/bpy as catalyst system. The crystalline behavior of PEO block in the copolymer was studied using differential scanning calorimetry(DSC) 、 polarized optical microscope(POM). It showed that the crystalizing velocity, crystallinity degree and crystalline perfection of PEO decreased as the content PS increased. Even there was no crystallization of PEO block. 2. A series of ABC triblock rod-coil liquid-crystalline copolymers with controlled molecular weight and narrow molecular weight distribution were obtained by ATRP using PEO-b-PS-Br as macroinitiators and CuBr/sparteine complex as catalyst system. Gel permeation chromatography(GPC) and 1HNMR were used to confirmed the structure of rod-coil block PMPCS. The liquid crystalline of this block copolymer was characterized by differential II 提 要 近几年来，随着现代科学技术