污泥活性炭的制备及其在焦化废水中的应用.pdfVIP

Vol.26 No.3 安徽工业大学学报 第26 卷 第3 期 July 2009 J. of Anhui University of Technology 2009 年 7 月 文章编号：1671-7872 （2009）03-0267-04 污泥活性炭的制备及其在焦化废水中的应用 陶冬民，孟冠华，欧承慧，刘宝河 （安徽工业大学建筑工程学院，安徽马鞍山243002） 摘要：研究了以城市污水厂脱水污泥为原料，氯化锌为活化剂的污泥活性炭制备工艺及其在焦化废水中的应用。在活化温度为 550 ℃、活化剂浓度为5 mol/L、固液比1:2 及活化时间40 min 条件下，制备得到的活性炭亚甲基蓝吸附值为 145.35 mg /g，BET 2 比表面积值为297.36 m /g 。将制备的污泥活性炭产品应用于焦化废水中，实验结果表明：污泥活性炭的最佳投加量为3 g/L，室 温下，吸附时间360 min，脱色率和COD 去除率分别可达到96.55 %与82.95 %。 关键词：污泥；活性炭；焦化废水；脱色率；COD 去除率 中图分类号：X703.1 文献标识码：A doi:10.3969/j.issn.1671-7872.2009.03.017 Activated Carbons Developed from Surplus Sewage Sludge for the Application to Coking Waste Water TAO Dong-min, MENG Guan-hua, OU Cheng-hui, LIU Bao-he (School of Civil Engineering Architecture, Anhui University of Technology, Ma′anshan 243002, China) Abstract: The preparation technology of sludge activated carbon using municipal dewatered sludge was studied. Zinc chloride (ZnCl ) was used as a sludge activation agent during the pyrolytic process. It was showed that the 2 technical conditions for preparation of sewage sludge-based activated carbon were activated temperature of 450 ℃, the concentration of ZnCl2 5 mol/L, solid-to-liquid quality ratio of 1:2, activation time of 40 min. Under the 2 conditions, The values methylene blue was 145.35 mg/g, BET surface was more than 297.36 m /g. Meanwhile, the adsorbent gained was used to treat coking waste water, with the optimal dosage of 3 g/L, in the room temperature and 360 min of adsorbing ti