基于唑类配体的配位聚合物的合成 结构和性质分析-synthesis structure and properties analysis of coordination polymers based on azole ligands.docxVIP

方式的多样性是研究的热点，因此我们利用氰基吡啶、叠氮离子直接与金属离子利用原位合成的方法得到了配位聚合物 6。该配合物是基于叠氮-吡啶-四唑基三元混桥联 的四核 Co（II）单元构筑的三维结构。Co1、Co2、Co3、Co4 之间以三重-二重-三重 桥的形式围成一个半圆形结构，Co1 和 Co4 离子则分别通过有机配体上的四唑环的一 个 1，4 位氮原子桥联连接形成了沿着 c 方向的一维链状结构，链通过 μ3-1,1,3-N3 桥 联方式构成了二维层,层与层直接通过辅助配体形成三维结构。磁性分析表明：Co(II) 离子在多元混桥之间传递着反铁磁相互作用。关键词：配位聚合物；晶体结构；桥联配体；磁性Syntheses, structures and characterization of coordination polymers based on azole ligandsAbstract: In recent years, the research of molecular magnetic materials based on coordination compounds have attracted considerable attention in the most fields. The azide ion is able to effectively propagate the magnetic exchange as bridging ligands, and has rich coordination model, with the organic ligands work together to build a variety of coordination polymers.In this thesis, a series of complexes with 1D, 2D and 3D structures were synthesized by transition metal ions, isoxazolecarboxylic acid or pyridine derivatives and characterized by single crystal X-ray analysis, elemental analyses, IR , and the part of them have also been studied by variable-field magnetic measurements. This thesis based on the following aspects:Coordination compounds with pyridyimidazoleThe pyridyimidazole can provide rich N source as organic ligand. In recent years, pyridine imidazole and its derivatives have been widely studied, but coordination mode has seldom reported.Three Co(II) ,Mn(II), Cu(II)coordination compounds (1-3) with N-(4-pyridylmethyl）imidazole (4-pyim) as auxiliary ligand and N3- as ligand were synthesized and characterized. Single-crystal X-ray structural analysis revealed that twocoordination polymers ( 1 and 2 ) are isomorphous. the unique Co(II) resides at a crystallographic inversion center and exhibits a octahedral coordination geometry. The adjacent Co(II) ions are connected by the 4-pyim ligands to form a 2D layer structure. The layers are further stacked in the ABAB mode to generate a entangled double-layer network. The thermal properties and electrochemical properties of comp