净水工艺中臭氧化单元优化控制副产物中试分析-pilot - scale analysis of optimal control by-products of ozonation unit in water purification process.docxVIP

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净水工艺中臭氧化单元优化控制副产物中试分析-pilot - scale analysis of optimal control by-products of ozonation unit in water purification process.docx

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净水工艺中臭氧化单元优化控制副产物中试分析-pilot - scale analysis of optimal control by-products of ozonation unit in water purification process

AbstractAs a kind of advanced treatment of drinking water, O3-GAC process has been more and more widely used in our Country. But ozonation of drinking water containing bromide may lead to the formation of bromate and the increase of AOC content, the removal effect of nitrobenzene and petroleum remains to be verified. By taking the raw water in Shenzhen area as the research object, the best way of pre-oxidation and the main ozone dosage were obtained by the optimization of O3-GAC process. The optimized process can reduced the concentration of by-products while removing pollutants effectly, and ensure the safety of effluent.Firstly, the pre-oxidation way of conventional water treatment process was studied in detail. The results showed that pre-oxidation significantly improved the water treatment effect of conventional process, and the removal rate of TOC, UV254, petroleum and nitrobenzene was increased 27%, 47%, 22% and 59%, respectively. Compared with water treatment effect and by-products control effect of potassium permanganate pre-oxidation and pre-ozonation, the results showed that petroleum has a better removal effect by potassium permanganate per-oxidation, and no bromate in effluent, the formation amount of AOC was lower than pre-ozonation. The removal capacity of nitrobenzene was powerful by pre-ozonation. TOC, UV254, turbidity have a better removal effect.Secondly, we made an optimization study on the main ozone dosing quantity of advanced treatment. The rusults showed that each pollutant has a good removal effect when the ozone concentration was 1.5 mg/L. In the ozone concentration, the bromate of effluent could reach the standard, and AOC could drop to a lower level, the effluent belonged to bio-stability. The removal effect of pollutants changed very little when the concentration of ozone was increased, the bromate content exceeding standard in effluent.Finally, the optimized condition of different water quality was proposed by the comprehensive analysis