具有β-ca3po42结构的发光材料的研究-study on luminescent materials with β - ca3po4 structure.docxVIP

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具有β-ca3po42结构的发光材料的研究-study on luminescent materials with β - ca3po4 structure.docx

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具有β-ca3po42结构的发光材料的研究-study on luminescent materials with β - ca3po4 structure

AbstractTheluminescentmaterialsdopedwithrareeartharewidelyusedinillumination, displaytechnoligiesanddetection.Theinvestigationsofluminescentmaterialshavea greatimportanceastheyplayadecisiveroleintheluminescencepropertiesofthe compactfluorescentlampandLEDs.PhosphorswiththematrixofPhosphateand Vanadatehavebeen extensivelyinvestigateddueto theirgood thermalstability, low temperaturesynthesisandgoodluminescencepropertiesunderUVirradiation.Inthis paper,weselectthecompoundsCa9ZnLi(PO4)7,Ca9Ln(PO4)7(Ln=Y,Gd)and Ca9A(VO4)7(A =Bi,La,Gd,Y)withtheβ-Ca3(PO4)2structureasthehosts,respectively. NewphosphorsaresynthesizedwiththeactivatorsCe3+,Tb3+,Mn2+ andEu3+,utilizing theactivatorionsoccupyingdifferentsitesinthehostsandtheenergytransferbetween them.TheXRD,PLandalsoothertestingmethodsareusedtostudytheimpactofthesynthesisconditionsanddopingconcentrationonthestructureandluminescence properties.Besides,theirluminescentmechanismandchromaticityhavebeenanalysed and calculated.ThephosphorsCa9ZnLi(PO4)7:Ce3+,Tb3+(orMn2+)werepreparedbysolid-statereaction.Bothoftheirexcitationspectraarebroadbandswiththepeakataround320nm, andexistedaresonance-typeenergytransferfromCe3+toTb3+orMn2+.Thecritical distancebetweentheactivatorionswerecalculated.Therelativeintensitiesofgreenorred emissioncouldbetunedbyadjustingthedopantconcentration.Greenphosphor Ca9Ln(PO4)7:Ce3+,Tb3+(Ln=Y,Gd)exhibitsblueandgreenemissionbandswasalso preparedbysolid-statereaction.Astheresonance-typeenergytransferfromCe3+toTb3+existed,thesensitizerofCe3+couldeffectivelyenhancethegreenemissionofTb3+.Asthe Tb3+concentrationincreases,thePLintensityincreasesandnoconcentrationquenchingis observedintherangeofourexperiment.Ca9A(VO4)7:Eu3+(A=Bi,La,Gd,Y)were synthesized by sol-gel method, and obtained the optimal synthesis conditions. Thestrongestemissionintensitypeakedat614nmwhichresultsfromtheelectricdipole transition5D0-7F2ofEu3+.AnefficientenergytransferfromVO43-grouptoEu3+hastaken place.TheCa9Eu(VO4)7 phosphorhasthestrongestredemissionin