NMR Characterization of Sidewall Functionalized SWNT[侧壁功能化的SWNT的NMR表征](PPT-31).pptVIP

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NMR Characterization of Sidewall Functionalized SWNT[侧壁功能化的SWNT的NMR表征](PPT-31).ppt

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NMR Characterization of Sidewall Functionalized SWNT[侧壁功能化的SWNT的NMR表征](PPT-31)

NMR Characterization of Sidewall Functionalized SWNT By Heather Rhoads Abstract Since the discovery of SWNT (Single walled carbon nanotubes) there has been an intense effort to characterize, understand, and exploit their properties.1, 2 To achieve the full potential of SWNT, they must be debundled into individual SWNTs. Debundling is achieve through several techniques including sidewall functionalization. The functionalization must be proven but currently utilized techniques give little information about the functionalization. More recently nuclear magnetic resonance (NMR) has been utilized to prove functionalization and the structure of the functionalized SWNT. This paper gives background, theory, review of the literature, and future directions. Background SWNT discovery Iijima in 1991 Avg Diameter of 1 nm Length up to 5 cm Produced by Arc discharge Laser ablation Chemical vapor deposition (CVD) Literature Review First utilized on Multiwalled carbon nanotubes3-5 Theoretical background calculations6-10 Location of SWNT in 13C NMR Separation of types of SWNT Properties Structural, electronic, phase transitions, and dynamics11 Theoretical separation of metallic and semiconducting12 Cutting, bending twisting and defects effect electronic properties13-14 Literature Review (cont) Growth Mechanism study15-17 Monitor opening and closing of SWNT18 Hydrogen gas storage19-23 Adsorption sites and mechanism24-27 Lithium and Cesium Intercalated28-33 Polymers and SWNT interactions34-42 Desired Properties of SWNT Electrical – 1000x greater than copper Mechanical - specific strength is aprox. 200x greater than steel Elastic – 5x greater than steel Characteristics of SWNT SWNT is a rolled up graphene sheet Composed of sp2 hybirderized carbon Hexagonal pattern Rolling along the hexagonal pattern forms along chiral vector a1, a2 giving units (n, m) Given by the following equation: Ch = n (a1) + m (a2) Vector units of SWNT Properties Determined by Chiral Vector Diameter - dt = (?3