USP38附录191一般鉴别试验.docVIP

USP32 附录191一般鉴别试验： 主要的问题是里面的一些英文and是翻译成“和”还是“或” Under this heading are placed tests that are frequently referred to in the Pharmacopeia for the identification of official articles.?Before using any acid or base to modify the PH of the sample solution, make sure that the added substance will not interfere with the results of the test. [NOTE—The tests are not intended to be applicable to mixtures of substances unless so specified.] 此处列举的检查项目都是频繁应用于药典鉴别项下的内容。在用任何酸或基础物质调整样品溶液的PH前，要保证所加的物质不会影响到检测结果：（注：除另有规定外，不适用于混合物） Acetate—Dissolve about 30mg of the substance to be examined in 3ml of the prescribed solution. Adjust the PH of the solution with sodium hydroxide to slightly alkaline. Add 0.25ml of lanthanum nitrate TS. If a white precipitate is formed, filter the solution. Add successively 0.1ml of iodine and potassium iodide TS 3 and 0.1ml of ammonia TS 2 to the solution. I f no blue color is observed, heat carefully to boiling. In the presence of acetates, a dark color develops or a blue precipitate is fprmed. With neureal solutions of acetates, ferric chloride TS produces a red color tha is destroyed by the addition of mineral acids.? 醋酸盐：将30mg被检物溶于3ml的水中，或用3ml的规定溶液。用氢氧化钠调节PH至弱碱。加入0.25ml硝酸镧试液。如出现白色沉淀，过滤溶液。先后加入0.1ml的碘和碘化钾试液3和0.1ml的氨试液至溶液中。如没得到蓝色，小心加热至沸腾。如硝酸盐出现深色或蓝色沉淀物。取醋酸的中性溶液，加三氯化铁试液出现红色，加无机酸，红色破坏。Aluminum—?With 6 N ammonium hydroxide, solutions of aluminum salts yield a gelatinous, white precipitate that is insoluble in an excess of 6 N ammonium hydroxide. 1 N sodium hydroxide or sodium sulfide TS produces the same precipitate, which dissolves in an excess of either of these reagents. 铝：1、加入6N的氨水，应产生白色胶状沉淀，沉淀物在过量的6N的氨水中不溶。2、加入1N的氢氧化钠或硫化钠试液，应产生白色胶状沉淀，当上述试液过量时，沉淀应溶解。 Ammonium—?Add 0.2g of magnesium oxide to the solution under test. Pass a current of air through the mixture, and direct the gas that escapes to just beneath the surface of an indicator solution, prepared by mixing 1ml of 0.1M hydrochloric acid and 0.05ml of methyl red TS2. In the presence of ammonium, the c