脂类的氧化oxidation.ppt

AUTOOXIDATION of LIPIDS Activation Energy for Food Chemical Reactions Mechanisms of Oxidation in Foods Molecular Orbital of Triplet Oxygen Molecular Orbital of Singlet Oxygen Comparison of 3O2 and 1O2 Molecular Orbital of Triplet Oxygen General Mechanisms of Autoxidation Major Chemical Mechanisms of Lipid Oxidation Factors Affecting Autoxidation Mechanisms of Oxidation Oxidation of Mono-Olefines Hydroperoxides from Linolenate Peroxide Decomposition Effects of Metal on Peroxide Decomposition Formation of C C * * Reactions Activation Energy (Kcal/Mole) Nonenzymatic Browning Reaction 50 Enzyme Catalyzed Reaction 10-15 Singlet Oxygen Oxidation 1-2 Flavor Quality Consumer Acceptance Nutritional Quality Essential Fatty Acids Essential Amino Acids Vitamins Health Risks Growth Retardation Heart Diseases Carcinogens Oxidation of Foods Oxygen History 1772 Scheele Priestley Discovered Oxygen ? 1811 Avogadro Oxygen is a diatomic molecule ? 1848 Faraday Oxygen is a paramagnetic molecule ? 1934 Herzberg Discovered singlet oxygen ? 1964 Foote Wexler Singlet oxygen in photooxidation ? Triplet oxygen oxidation Singlet oxygen oxidation Energy ?* ? 2S 2S 2Px 2Py 2Pz 2Pz 2Py 2Px ? ? ? ?* ?* ?* Molecular Atomic Atomic ?* ? 1S 1S Energy ?* ? 2S 2S 2Px 2Py 2Pz 2Pz 2Py 2Px ? ? ? ?* ?* ?* Molecular Atomic Atomic ?* ? 1S 1S 3O2 1O2 ENERGY LEVEL 0 22.5 Kcal NATURE