三价铁合成lifepo4及其性能的研究-材料加工工程专业论文.docxVIP

山东科技大学硕士学位论文摘要 山东科技大学硕士学位论文 摘要 1 1 摘 要 在能源问题越来越严峻的今天，磷酸铁锂正极作为最新一代的锂离子电池正极材料， 由于其原料来源丰富，环境污染小，比容量高，循环性能优良等优点而备受关注。但是 较低的锂离子扩散系数和低导电率成为制约其发展的一个障碍。本文以三价的硝酸铁， 磷酸氢二氨，蔗糖和碳酸锂为主要原料，采用两步合成法制备出 LiFePO 4/C 复合材料。 并通过 XRD、SEM 和充放电测试等实验手段对前躯体及正极材料的合成条件，形貌及 电化学性能进行研究。 文章研究了在不同的反应物初始浓度，pH 值，搅拌时间，对制备前躯体和正极材料的 影响。结果表明在反应浓度为 0.1mol/L，pH 值为 2.0，搅拌时间为 6h 时得到的前驱体及 正极材料的颗粒较均匀，并接近球形，在同组实验中的比容量及循环性能最佳。 以 Cu 锂离子为掺杂元素，在用液相法合成前躯体时对前躯体进行掺杂并合成正极材 料，结果发现在掺杂质量分数为 2%时第一次充放电比容量达到 140mAh/g，循环性能也 较好。 关键词：锂离子电池，正极材料，LiFePO4 ，前躯体，反应条件 山东科技大学硕士学位论文Ab 山东科技大学硕士学位论文 Abstract Abstract Nowadays, with the problem of energy come to be a big question, as one kind of the most promising cathode material ,the olivine LiFePO4 has got much attention for the advantages as follow: abundant raw material, low cost, little environment pollution, high energy density and stable cycle performance. But it has low electronic conductivity and lithium ion diffusivity which will be a huge problem to limit its development. In this paper, the cathode materials was synthesized by two-step reaction with Fe(NO3)3, Li2CO3, (NH4)2HPO4, C12H22O11,etc. The materials’ synthesis factors、surface morphology, structure and electrochemical performance were studied through measures such as XRD, SEM, and charge-discharge tests. The effects of the solution’s consistency, pH value and stir time on FePO4 and cathode materials’ physical properties and electrochemical performance were investigated. The results indicated that materials prepared under consistency as 0.1mol/L and pH value as 2.0 and stir time as 6h has better surface morphology and electrochemical performance. Cathode materials was prepared with Cu2+ being dopant, and the results indicate that specific capacity first charge-discharge come to 140mAh/g with Cu2+ take 2 wt% percent , and the cycle performance will be better, too. 2 2 Keywords : Lithium ion battery, cathode material, LiFePO4 ； Preparation, Reaction condition 1 1 山东科技大学硕士学位论文