凹凸棒石黏土-腐植酸复合吸附剂的制备及其吸附性能分析-preparation and adsorption performance analysis of attapulgite clay - humic acid composite adsorbent.docxVIP

AbstractWastewaterstillcausesgreatharmtotheenvironmentandhumanhealthwiththerapiddevelopmentofindustry,increasinglystringentemissionstandards.Therefore,recyclingofwateriswidelyattention,theroleofadsorptionmethodinwastewatertreatmentwillbecomeincreasinglyimportant.Seekinganddevelopingefficientlow-costadsorbentsbecomethekeyissueofthestudy.Inthispaper,modifiedattapulgiteclaywaspreparedthroughpurification,acidificationandthermalactivationofattapulgiteclaymineralsfromBaiyincityinGansuprovince,andwasaddedtothehumicacidfromligniteinTianzhu,withthismethodattapulgite-humicacidcompositeadsorbentwasprepared.Comparedtheadsorptionpropertiesofthecompositeadsorbentwithanothertwoseparateadsorbents,andadsorptionconditionswereoptimizedthroughthecombinationofasinglefactorandorthogonalexperiments,suchastheeffectofadsorbentproportion,thedosage,temperature,pHvalue,adsorptiontimeandtheconcentrationoftheadsorbatetoadsorptionefficiency.TheadsorbentwerecharacterizedandanalyzedbyInfraredSpectroscopy(FTIR),ScanningElectronMicroscopy,XRDandanotherdetectiontechnologies.Foundthattheparticlesizeofthecompositeadsorbentissmallanduniform,specificsurfaceareaandsurfaceactivegroupshavebeengreatlyimproved.Byoptimizingtheexperimentalconditions,thecompositeadsorbenthasagoodadsorptionperformancetoNi2+,Mn2+,phosphateandmethyleneblue.ThebestadsorptionconditionsofNi2+aretheconcentrationof150mg/L,adsorbentdosageof0.8g,adsorptiontimeof4h,thetemperatureof40℃,pHof6,theadsorptionratereaches97.5%withtheadsorptioncapacityof9.14mg/g.ThebestadsorptionconditionsofMn2+aretheconcentrationof100mg/L,adsorbentdosageof0.8g,adsorptiontimeof2h,thetemperatureof40℃,pHof7,theadsorptionratereaches92.5%withtheadsorptioncapacityof5.78mg/g.Thebestadsorptionconditionsofphosphatearetheconcentrationof100mg/L,adsorbentdosageof0.8g,adsorptiontimeof4h,thetemperatureof80℃,pHof5,theadsorptionratereaches91.5%withtheadsorptioncapacityof5.72mg/g.Thebestadsorptionconditionsofmethylenebluearetheconcentrationof300mg/L,adsorbentdosageof0.3g,adsorptio