凹凸棒石—铁氧化物复合材料对有机物吸附分析-adsorption analysis of organic matter by attapulgite - iron oxide composite material.docxVIP

Attapulgite-ironoxidecompositeadsorptionstudiesoforganicmatterAbstractDCP/BPAisanorganicpollutantadsorptionpropertiesoftwoorganicpollutantsbythestaticassayPMCmaterial;theadsorptionregenerationexperiments,theregenerationefficiencybyFentonregenerationwithpotassiumpermanganateregenerationresearch.Throughaseriesofexperiments,thefollowingconclusions:Underacidicconditions(pH5),thesinglefactortestadsorbedinthethePMCmaterialonDCPtopromoteitsadsorption;TheincreasedconcentrationofCu2+promotetheadsorptionprocess;ByadsorptionisothermfittingFreundlichadsorptionmodelcanfittheadsorptionbehavior.PMCmaterialadsorptiontheDCPkineticsequationmodelfitting,thesecondorderkineticmodeltobetterfittheadsorptionprocess,theadsorptionrateparametersbasicR2≥0.99;Andtheadsorptionprocessissurfaceadsorptionandintra-particlediffusionprocess.ComparePMContheDCP/BPAoftheadsorptionprocess,thethePMCmaterialonBPAisfastadsorption;PMCofBPAadsorptionsurfaceadsorptionprocessinthekineticsoftheadsorptionfitting.BPApolaritylessthanDCPhydrophobicPMCmaterialmorereadilyadsorbableweaklypolarorganiccompounds.ThePMCmaterialFentonregenerationconditionsforH2O2dosageis0.5mLFe2SO4dosageof100mg/L,themaximumregenerationefficiencyof98.01%;potassiumpermanganateregenerantasthebestregenerationconditionsinneutralandalkalinepH,potassiumpermanganatedosage20mL/gmaximumregenerationefficiency,maximumregenerationefficiencyof98.28%.Fentonrecycledequilibriumregenerationefficiencyof42.8%and99.17%ofthethepotassiumpermanganaterecycleditsbalanceregenerationrate.Keywords:Attapulgite;Wasteactivatedclay;Ironsalts;Organicmatter;Regeneration致谢三年过去，我的研究生学习生活也结束。首先非常感谢我的导师——庆承松教授和陈天虎教授，在我的研究生学习阶段给予了我无微不至的关怀。从最初的定题，阅读资料，到实验操作，再到论文写作、修改及定稿，陈老师都给了我无私的帮助和耐心的指导。正是老师耐心诚恳的教导使我的实验学习和科研方面获得了很大收益。导师的一言一行，使我深切感受到了一位科研工作者精益求精的工作作风，严谨高尚的学术操守和平易近人的处世情怀。在此，我要向导师表示最衷心的感谢和最深切的敬意！其次，特别感谢陈冬老师在实验过程中的指导和论文撰写过程中给予我宝贵的意见和建议，在此对他们表示由衷的敬意和诚挚的感谢。在研究生学习阶段，还得到了课题组成员刘海波、孔殿超、鲍腾等师兄，汪国威、谢芸芸、姚敦璠、杨燕等同窗好友，以及韦玲、李碧等师妹们的关心和帮助，在此表示深深的谢意。最后，向参加评议和审阅本论文的各位专家、老师和参加答辩的全体老师表示我深深的谢意!作者：滕沙沙2013