卟啉类席夫碱的合成及性能分析-synthesis and properties analysis of porphyrin schiff bases.docxVIP

较单卟啉均发生不同程度的红移，敏化的纳米 TiO2 薄膜的紫外-可见光谱与溶液相比红 移并加宽；它们的激发态能级范围在-0.90 V ~ -1.08 V 之间，与纳米 TiO2 导带能级位置 相匹配；总的光电转换效率(η)分别是：0.65%，0.75%，0.86%，2.44%，2.86%，得到了 较好的光电性能。关键词 席夫碱，卟啉，合成，光电性能，染料敏化剂太阳能电池Synthesis, characterization and properties of porphyrins Schiff base photosensitizersAbstractPorphyrins are a kind of highly conjugated system of 24 center 26 electron,which have good thermal stability, chemical stability, and the significant efficiency and rate of electron injection. In addition, porphyrins have strong modification, can introduce different substituents, which have been widely applied in every fields; Due to C =N bond, theschiff base compounds show the good electro-optical properties, and the synthesis of that is simple, so they have been used as functional materials. In this paper, five new schif-f base porphyrin-sensitized dyes have been synthesised successfully and applied in dye-sensitized solar cells, including three kinds of symmetric schiff base porphyrins, two kinds of schiff base porphyrin dimers, Though the introduction of different substituents and C=N bonds, the molecular structure are changed to expanded spectral range, make electron directivity in dye molecules, and to improve the photoelectric properties.Five new schif-f base porphyrin-sensitized dyes were synthesized by imidazole, 4-fluorobenzaldehyde, redistilled pyrrole, benzaldehyde, 4-nitrobenzaldehyde, 2-Thiophene- carboxaldehyde, p-methyl benzaldehyde, paraformaldehyde, zinc chloride, hexamethyl enetet-ramine, zinc acetate, which were meso- tetra [p-(p-benzal imido)] phenyl zinc porphyrin (Ⅱ)(TBIPP-Zn), meso-tetra [p-(2-thenylidene imido)] phenyl zinc porphyrin(Ⅱ)(TTIPP-Zn), meso-tetra[p-(p-N-imidazolyl benzal imido)] phenyl zinc porphyrin(Ⅱ)(TIIPP-Zn),p-(10,15,20-triphenyl-5-porphyrinyl) benzylidene aminophenyl-10,15,20-(p-methylphenyl) porphyrin (TPBAMP), p-(10,15,20-triphenyl-5-porphyrinyl) benzylidene aminophenyl-10,15, 20- (2-thienyl)porphyrin (TPBATP).The structure of the fiv