苯选择加氢与环己烯水合绿色集成系统的分析-analysis of green integrated system of benzene selective hydrogenation and cyclohexene hydration.docx

苯选择加氢与环己烯水合绿色集成系统的研究zeolite was 25. It was proved by acidic characterization that the strong Br?nsted acid sites were the active sites of cyclohexene hydration. Under the optimum conditions, the highest cyclohexene conversion was 11.8% with 98.7% cyclohexanol selectivity. Effect of different kinds of organic solvents on cyclohexene hydration was studied, and the optimal organic solvent was selected. The reaction conditions of cyclohexene hydration with solvents were optimized. Under the most suitable conditions, the highest cyclohexene conversion was 34.5%, the cyclohexanol selectivity was 99.3%.HZSM-5 zeolite was synthesized using various templates. HZSM-5 zeolite synthesized using aluminum nitrate (Al(NO3)3), tetraethyl orthosilicate (TEOS), and tetrapropyl ammonium hydroxide (TPAOH) as raw materials was mainly studied. The effects of pH regulators, SiO2/Al2O3 ratio, crystallization temperature and surfactants on morphology and particle size of HZSM-5 zeolite were investigated. Because the HZSM-5 zeolite with regular morphology and small particle size could provide more active sites in cyclohexene hydration, it could obtain cyclohexanol 12.3% yield. On the basis of HZSM-5 zeolite synthesis, HZSM-5 zeolite membranes were synthesized on irregular supports by in situ hydrothermal synthesis method, pre-seeding method and self-assembly seeding method. The differences of these HZSM-5 zeolite membranes synthesized by different methods were studied.A new multi-functional composite catalyst for the integration reaction was prepared with Ru-Zn catalyst or Ru-Zn/SiO2 catalyst as core, HZSM-5 zeolite membrane as shell. The green integrated system of benzene selective hydrogenation and cyclohexene hydration in nano-scale was established on the Ru-Zn@HZSM-5 and Ru-Zn/SiO2@HZSM-5 catalysts. The green integrated system of benzene selective hydrogenation and cyclohexene hydration in micro-scale was established on the mechanical mixed Ru-Zn+HZSM-5 catalyst. A dynamic operat